The extent to which cations and anions in ionic liquids (ILs) and ionic liquid solutions are
dissociated is of both fundamental scientific interest and practical importance because ion …

Vibrational spectroscopy has continued use as a powerful tool to characterize ionic liquids
since the literature on room temperature molten salts experienced the rapid increase in …

The effect of the anion size and electronegativity of halide-based anions (Cl–, Br–, I–, and
BF4–) on the interionic interaction in 1-ethyl-3-methylimidazolium-based ionic liquids (ILs) …

Hydrogen bonding (H-bonding) is an important and very general phenomenon. H-bonding
is part of the basis of life in DNA, key in controlling the properties of water and ice, and …

We address the competition between intermolecular forces underlying the recent
observation that ionic liquids (ILs) with a hydroxyl-functionalized cation can form domains …

This study explores the interactions underlying the IR spectra of the ionic liquid
[NC4111][NTf2] and its deuterated isotopomer [d9-NC4111][NTf2] by first isolating the …

We address the cooperative hydrogen bonding interactions in play between the ionic
constituents of ionic liquids (ILs) with particular attention to those involving the attractive …

The properties of ionic liquid (1-ethyl-3-methylimidazolium BF 4 and 1-butyl-3-
methylimidazolium BF 4)+ solvents (water, ethylene glycol or dimethylformamide) mixtures …

The infrared predissociation spectra of [bmim]+·(H2O) n, n= 1–8, in the 2800–3800 cm− 1
region are presented and analyzed with the help of electronic structure calculations. The …

The accumulation of ions at electrochemical interfaces governs the local chemical
environment, which in turn determines the reaction pathways and rates of electrocatalytic …