Proton transfer kinetics of transition metal hydride complexes and implications for fuel-forming reactions
CL Montgomery, J Amtawong, AM Jordan… - Chemical Society …, 2023 - pubs.rsc.org
Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …
[HTML][HTML] The ferrocenium/ferrocene couple: a versatile redox switch
L Fabbrizzi - ChemTexts, 2020 - Springer
Woodward and co-workers in 1952 characterised the unique structural features of ferrocene
(the first sandwich compound), demonstrated its aromatic nature and observed that on …
(the first sandwich compound), demonstrated its aromatic nature and observed that on …
The power of the proton: from superacidic media to superelectrophile catalysis
HFT Klare, M Oestreich - Journal of the American Chemical …, 2021 - ACS Publications
Superacidic media became famous in connection with carbocations. Yet not all reactive
intermediates can be generated, characterized, and eventually isolated from these Brønsted …
intermediates can be generated, characterized, and eventually isolated from these Brønsted …
Quantum crystallography: Current developments and future perspectives
A Genoni, L Bučinský, N Claiser… - … A European Journal, 2018 - Wiley Online Library
Crystallography and quantum mechanics have always been tightly connected because
reliable quantum mechanical models are needed to determine crystal structures. Due to this …
reliable quantum mechanical models are needed to determine crystal structures. Due to this …
Cp* noninnocence leads to a remarkably weak C–H bond via metallocene protonation
Metallocenes, including their permethylated variants, are extremely important in
organometallic chemistry. In particular, many are synthetically useful either as oxidants (eg …
organometallic chemistry. In particular, many are synthetically useful either as oxidants (eg …
Mechanistic roles of metal-and ligand-protonated species in hydrogen evolution with [Cp* Rh] complexes
Protonation reactions involving organometallic complexes are ubiquitous in redox chemistry
and often result in the generation of reactive metal hydrides. However, some organometallic …
and often result in the generation of reactive metal hydrides. However, some organometallic …
Cyclopentadienyl ring activation in organometallic chemistry and catalysis
A VanderWeide, DE Prokopchuk - Nature Reviews Chemistry, 2023 - nature.com
The cyclopentadienyl (Cp) ligand is a cornerstone of modern organometallic chemistry.
Since the discovery of ferrocene, the Cp ligand and its various derivatives have become …
Since the discovery of ferrocene, the Cp ligand and its various derivatives have become …
[HTML][HTML] Photooxidation driven formation of Fe-Au linked ferrocene-based single-molecule junctions
Metal-metal contacts, though not yet widely realized, may provide exciting opportunities to
serve as tunable and functional interfaces in single-molecule devices. One of the simplest …
serve as tunable and functional interfaces in single-molecule devices. One of the simplest …
Magnetically Induced Binary Ferrocene with Oxidized Iron
Ferrocene is perhaps the most popular and well-studied organometallic molecule, but our
understanding of its structure and electronic properties has not changed for more than 70 …
understanding of its structure and electronic properties has not changed for more than 70 …
Synthesis and Reactivity of an End‐Deck cyclo‐P4 Iron Complex
A Cavaillé, N Saffon‐Merceron, N Nebra… - Angewandte Chemie …, 2018 - Wiley Online Library
Reduction of the FeII complex [(PhPP2Cy) FeCl2](2) generated an electron‐rich and
unsaturated Fe0 species, which was reacted with white phosphorus. The resulting new …
unsaturated Fe0 species, which was reacted with white phosphorus. The resulting new …