Bonds over electrons: proton coupled electron transfer at solid–solution interfaces

JM Mayer - Journal of the American Chemical Society, 2023 - ACS Publications
This Perspective argues that most redox reactions of materials at an interface with a protic
solution involve net proton-coupled electron transfer (PCET)(or other cation-coupled ET) …

Photoinduced Electron Transfer Mediated by Coordination between Carboxyl on Carbon Nanodots and Cu2+ Quenching Photoluminescence

C Liu, B Tang, S Zhang, M Zhou, M Yang… - The Journal of …, 2018 - ACS Publications
Carbon nanodots (C-dots) have been widely used in sensing, such as detection of ions,
small molecules and biomolecules, based on their photoluminescence (PL) quenching by …

Solvent-modulated proton-coupled electron transfer in an iridium complex with an ESIPT ligand

S Kim, J Choi, DW Cho, M Ahn, S Eom, J Kim… - Chemical …, 2022 - pubs.rsc.org
Proton-coupled electron transfer (PCET), an essential process in nature with a well-known
example of photosynthesis, has recently been employed in metal complexes to improve the …

Spectroscopy of reactive complexes and solvated clusters: A bottom-up approach using cryogenic ion traps

E Garand - The Journal of Physical Chemistry A, 2018 - ACS Publications
In this paper, applications of cryogenic ion traps for forming reaction intermediates and
solvated clusters from precursor ions generated by electrospray ionization are presented …

Hydrogen bond assisted photoinduced intramolecular electron transfer and proton coupled electron transfer in an ultrafast time domain using a ruthenium …

A Dey, J Dana, S Aute, A Das, HN Ghosh - … & Photobiological Sciences, 2019 - Springer
Quinones play a significant role as primary electron acceptors in the natural photosynthetic
system of photosystem II, and their reduction is known to be facilitated by hydrogen-bond …

New insights on hydrogen-bond-induced fluorescence quenching mechanism of C102–phenol complex via proton coupled electron transfer

T Hossen, K Sahu - The Journal of Physical Chemistry A, 2018 - ACS Publications
The H-bonded coumarin 102 (C102)–phenol complex has been a model system usually
used to understand the influence of H-bonding on photophysical processes. Zhao and Han …

Discriminative behavior of a donor–acceptor–donor triad toward cyanide and fluoride: Insights into the mechanism of naphthalene diimide reduction by cyanide and …

B Chowdhury, S Sinha, R Dutta, S Mondal… - Inorganic …, 2020 - ACS Publications
A new molecular donor–acceptor–donor (D–A–D) triad, comprised of an electron deficient 1,
4, 5, 8-naphthalene tetracarboxylic diimide (NDI) unit covalently connected to two flanking …

Excited State Interaction of Ruthenium (II) Imidazole Phenanthroline Complex [Ru(bpy)2ipH]2+ with 1,4‐Benzoquinone: Simple Electron Transfer or Proton‐Coupled …

RV Khade, S Dutta Choudhury, H Pal… - …, 2018 - Wiley Online Library
The unidirectional proton coupled electron transfer (PCET) from the excited state of Ru (II)
imidazole phenanthroline complex [Ru (bpy) 2ipH] 2+ to 1, 4‐benzoquinone, was studied by …

Proton-coupled electron transfer for photoinduced generation of two-electron reduced species of quinone

A Dey, N Ghorai, A Das, HN Ghosh - The Journal of Physical …, 2020 - ACS Publications
Purpose-built molecules that follow the fundamental process of photosynthesis have
significance in developing better insight into the natural photosynthesis process. Quinones …

Effects of hydrogen bonding on intramolecular/intermolecular proton-coupled electron transfer using a Ruthenium-anthraquinone dyad in ultrafast time domain

A Dey, N Ghorai, A Das, HN Ghosh - Journal of Photochemistry and …, 2023 - Elsevier
A ruthenium-anthraquinone dyad consisting of the bi-imidazole spacer in which one
imidazole proton acts as a hydrogen bonding agent is employed to investigate the effects of …