Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials

F Franco, C Rettenmaier, HS Jeon… - Chemical Society …, 2020 - pubs.rsc.org
The electrochemical reduction of carbon dioxide (CO2) powered by renewable energy is an
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO2

Q Wu, RK Xie, MJ Mao, GL Chai, JD Yi… - ACS Energy …, 2020 - ACS Publications
Electroreduction of CO2 (CO2RR) into value-added fuels is of significant importance but
remains a big challenge because of poor selectivity, low current density, and large …

Durable Cathodes and Electrolyzers for the Efficient Aqueous Electrochemical Reduction of CO2

UO Nwabara, ER Cofell, S Verma, E Negro… - …, 2020 - Wiley Online Library
The world emits over 14 gigatons of CO2 in excess of what can be remediated by natural
processes annually, contributing to rising atmospheric CO2 levels and increasing global …

[HTML][HTML] Nickel polyphthalocyanine with electronic localization at the nickel site for enhanced CO2 reduction reaction

K Chen, M Cao, G Ni, S Chen, H Liao, L Zhu… - Applied Catalysis B …, 2022 - Elsevier
Nickel phthalocyanine (NiPc) can be at first glance a compelling catalyst for CO 2 reduction
reaction (CO 2 RR) because of its Ni–N 4 site. Unfortunately, the pristine NiPc possesses a …

Cobalt–N-heterocyclic carbene complexes in catalysis

SS Bera, M Szostak - ACS catalysis, 2022 - ACS Publications
Cobalt–N-heterocyclic carbene (NHC) complexes have emerged as an attractive class of 3d
transition metal catalysts for a broad range of chemical processes, including cross-coupling …

Enhancing a Molecular Electrocatalyst's Activity for CO2 Reduction by Simultaneously Modulating Three Substituent Effects

W Nie, DE Tarnopol, CCL McCrory - Journal of the American …, 2021 - ACS Publications
The electrocatalytic activity for CO2 reduction is greatly enhanced for Co complexes with
pyridyldiimine-based ligands through the stepwise integration of three synergistic …

Ligand-based redox: catalytic applications and mechanistic aspects

K Singh, A Kundu, D Adhikari - ACS Catalysis, 2022 - ACS Publications
For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …

Electrocatalytic CO2 Reduction: from Discrete Molecular Catalysts to Their Integrated Catalytic Materials

K Lei, B Yu Xia - Chemistry–A European Journal, 2022 - Wiley Online Library
Molecular catalysts (metal complexes), with molecularly defined uniform active sites and
atomically precise structural tailorability allowing for regulating catalytic performance …

Mechanistic Insights into Co and Fe Quaterpyridine-Based CO2 Reduction Catalysts: Metal–Ligand Orbital Interaction as the Key Driving Force for Distinct Pathways

M Loipersberger, DGA Cabral, DBK Chu… - Journal of the …, 2021 - ACS Publications
Both [CoII (qpy)(H2O) 2] 2+ and [FeII (qpy)(H2O) 2] 2+(with qpy= 2, 2′: 6′, 2 ″: 6′′, 2‴-
quaterpyridine) are efficient homogeneous electrocatalysts and photoelectrocatalysts for the …