Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Conversion of biomass into chemicals over metal catalysts

M Besson, P Gallezot, C Pinel - Chemical reviews, 2014 - ACS Publications
The catalytic conversion of biomass and derivatives to chemicals has been the subject of
intense research efforts during the past decade resulting in a 20% annual increase in the …

[HTML][HTML] Glucose-oxidase like catalytic mechanism of noble metal nanozymes

J Chen, Q Ma, M Li, D Chao, L Huang, W Wu… - Nature …, 2021 - nature.com
Au nanoparticles (NPs) have been found to be excellent glucose oxidase mimics, while the
catalytic processes have rarely been studied. Here, we reveal that the process of glucose …

[HTML][HTML] Kinetically restrained oxygen reduction to hydrogen peroxide with nearly 100% selectivity

J Chen, Q Ma, X Zheng, Y Fang, J Wang… - Nature …, 2022 - nature.com
Hydrogen peroxide has been synthesized mainly through the electrocatalytic and
photocatalytic oxygen reduction reaction in recent years. Herein, we synthesize a single …

Carbon materials as catalyst supports and catalysts in the transformation of biomass to fuels and chemicals

E Lam, JHT Luong - ACS catalysis, 2014 - ACS Publications
Carbon plays a dual role as a catalyst or a catalyst support for chemical and enzymatic
biomass transformation reactions due to its large specific surface area, high porosity …

Mechanism of pH-switchable peroxidase and catalase-like activities of gold, silver, platinum and palladium

J Li, W Liu, X Wu, X Gao - Biomaterials, 2015 - Elsevier
Despite being increasingly used as artificial enzymes, little has been known for the origin of
the pH-switchable peroxidase-like and catalase-like activities of metals. Using calculations …

Tafel kinetics of electrocatalytic reactions: from experiment to first-principles

YH Fang, ZP Liu - Acs Catalysis, 2014 - ACS Publications
The Tafel equation is of fundamental importance in electrochemical kinetics, formulating a
quantitative relation between the current and the applied electrochemical potential. The …

Selective oxidation of alcohols and aldehydes over supported metal nanoparticles

SE Davis, MS Ide, RJ Davis - Green Chemistry, 2013 - pubs.rsc.org
Oxidation is a key reaction in organic synthesis and will likely play a significant role in the
development of value-added chemicals from biomass. The application of heterogeneous …

Catalysis by supported gold nanoparticles: beyond aerobic oxidative processes

M Stratakis, H Garcia - Chemical Reviews, 2012 - ACS Publications
1. INTRODUCTION Bulk gold, being the most stable among all metals, was for many years
considered as an inert catalyst. However, gold particles with size on the scale of nanometers …

Nano-gold catalysis in fine chemical synthesis

Y Zhang, X Cui, F Shi, Y Deng - Chemical Reviews, 2012 - ACS Publications
Gold has been used for coinage, jewelry, and other arts for thousands of years due to its
stability in air. Catalytic researchers were long misled by this common sense until the …