Hydroelementation enables a facile reduction or functionalization of several unsaturated
systems, and thus activation of such bonds like B–H and Si–H is a powerful synthetic tool …

Tris [N, N-bis (trimethylsilyl) amido] lanthanum (LaNTMS) is an efficient, highly active, and
selective homogeneous catalyst for ester reduction with pinacolborane (HBpin). Alkyl and …

Transient Cu–H monomers have long been invoked in the mechanisms of substrate
insertion in Cu–H catalysis. Their role from Cu–H aggregates has been mostly inferred since …

We disclose a 1, 4, 7-triazacyclononane (TACN) ligand featuring an appended boron Lewis
acid. Metalation with Cu (I) affords a series of tetrahedral complexes including a boron …

Reductive catalysis with earth-abundant metals is currently of increasing importance and
shows potential in replacing precious metal catalysis. In this work, we revealed catalytic …

Cu (I)-Hydrido complexes supported by dibenzo [b, f] azepinyl P-alkene hybrid ligands and
stabilized by electrostatic interactions in a Cu–H⋯ KCl⋯ BR3 arrangement can be trapped …

Abstract Bis [(2-diphenylphosphino) phenyl] ether (DPEphos) was used as chelating ligand
to prepare the corresponding borohydride complex [Cu (κ 2–BH 4)(DPEphos)], whose …

Thermally sensitive polymeric zinc dihydride [ZnH2] n can conveniently be prepared by the
reaction of ZnEt2 with [AlH3 (NEt3)]. When reacted with CO2 (1 bar) in the presence of …

We present a series of borane‐tethered cyclic (alkyl)(amino) carbene (cAAC)‐copper
complexes, including a borane‐capped Cu (I) hydride. This hydride is unusually hydridic …

Fluoride abstraction from different types of transition metal fluoride complexes [LnMF](M= Ti,
Ni, Cu) by the Lewis acid tris (pentafluoroethyl) difluorophosphorane (C2F5) 3PF2 to yield …