Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Synergistic dual transition metal catalysis
UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …
enable a reaction between two separately activated substrates, has unlocked a plethora of …
Copper-catalyzed borylative difunctionalization of π-systems
Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …
Enantio‐and Diastereodivergent Synthesis of Spirocycles through Dual‐Metal‐Catalyzed [3+ 2] Annulation of 2‐Vinyloxiranes with Nucleophilic Dipoles
Y Peng, X Huo, Y Luo, L Wu, W Zhang - Angewandte Chemie, 2021 - Wiley Online Library
The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …
isomers of structurally rigid spirocycles from readily available starting materials is of great …
Recent developments in organoboron chemistry: old dogs, new tricks
JWB Fyfe, AJB Watson - Chem, 2017 - cell.com
Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …
Copper-boryl mediated organic synthesis
D Hemming, R Fritzemeier, SA Westcott… - Chemical Society …, 2018 - pubs.rsc.org
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …
diverse variety of processes including both C–X and C–C bond-forming transformations …
Nickel‐catalyzed asymmetric reductive diarylation of vinylarenes
A nickel‐catalyzed asymmetric diarylation reaction of vinylarenes enables the preparation of
chiral α, α, β‐triarylated ethane scaffolds, which exist in a number of biologically active …
chiral α, α, β‐triarylated ethane scaffolds, which exist in a number of biologically active …
Stereodivergent Pd/Cu catalysis for the dynamic kinetic asymmetric transformation of racemic unsymmetrical 1, 3-disubstituted allyl acetates
A stereodivergent Pd/Cu catalyst system has been developed for the unprecedented
dynamic kinetic asymmetric transformation (DyKAT) of racemic unsymmetrical 1, 3 …
dynamic kinetic asymmetric transformation (DyKAT) of racemic unsymmetrical 1, 3 …
Transition‐Metal‐Catalyzed Three‐Component Difunctionalizations of Alkenes
JS Zhang, L Liu, T Chen, LB Han - Chemistry–An Asian Journal, 2018 - Wiley Online Library
Three‐component reactions can directly convert three reactants into the desired products in
one pot and thus greatly shorten the synthetic path. Recently, transition‐metal catalysis has …
one pot and thus greatly shorten the synthetic path. Recently, transition‐metal catalysis has …
Asymmetric transformations enabled by synergistic dual transition-metal catalysis
L Wei, CJ Wang - Chem Catalysis, 2023 - cell.com
From its beginnings in the Sonogashira reaction, synergistic dual transition-metal catalysis
has gained increasing prominence and importance. In the past decade, this strategy has …
has gained increasing prominence and importance. In the past decade, this strategy has …