Emerging organometallic methods for the synthesis of C‐branched (hetero) aryl, alkenyl, and alkyl glycosides: C− H functionalization and dual photoredox …

J Ghouilem, M de Robichon… - … A European Journal, 2021 - Wiley Online Library
Transition‐metal‐catalyzed C− H functionalization and photoredox nickel dual catalysis
have emerged as innovative and powerful avenues for the synthesis of C‐branched …

Recent advances in palladium-catalyzed C (sp 3)/C (sp 2)–H bond functionalizations: access to C-branched glycosides

Z Azeem, PK Mandal - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Over the recent decades, tremendous interest has developed in the transformation of
complex substrates by C–H activation and functionalization. In particular, palladium …

Versatility of glycals in synthetic organic chemistry: coupling reactions, diversity oriented synthesis and natural product synthesis

HH Kinfe - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
Glycals, 1, 2-unsaturated sugar derivatives, are versatile starting materials for the synthesis
of natural products and the generation of novel structural features in Diversity Oriented …

Advances in Pd-catalyzed C–C bond formation in carbohydrates and their applications in the synthesis of natural products and medicinally relevant molecules

N Hussain, A Hussain - Rsc Advances, 2021 - pubs.rsc.org
Advances in the Pd-catalyzed synthesis of C-glycosides and branched sugars are
summarized herein and the strategies are categorized based on named reactions or types of …

Sonogashira cross-coupling as a key step in the synthesis of new glycoporphyrins

B Godlewski, D Baran, M de Robichon… - Organic Chemistry …, 2022 - pubs.rsc.org
Glycoporphyrins are an important subclass of the porphyrin family of compounds. They have
been intensively studied because of their biological importance, ie they exhibit increased …

Synthesis of (1→ 2)-S-linked saccharides and S-linked glycoconjugates via a Palladium-G3-XantPhos precatalyst catalysis

RAA Al-Shuaeeb, D Montoir, M Alami… - The Journal of Organic …, 2017 - ACS Publications
Buchwald–Hartwig–Migita cross-coupling of 1-thiosugars with 2-iodoglycals has been
accomplished under mild and operationally simple reaction conditions through the use of Pd …

Pd-catalyzed direct functionalization of glycals with cycloalkenones: application to the synthesis of chiral phenanthrenones

M Maheshwari, RP Pandey, N Hussain - Chemical Communications, 2023 - pubs.rsc.org
A palladium-catalyzed direct C–H functionalization of glycals with cycloalkenones is
described and a series of C-2 functionalized glycals were synthesized efficiently with cyclic …

Recent advances in transition‐metal‐catalyzed functionalization of 1‐thiosugars

N Ibrahim, M Alami, S Messaoudi - Asian Journal of Organic …, 2018 - Wiley Online Library
Thioglycosides are valuable glycomimetic derivatives that have attracted much attention as
mimetics of O‐glycosides. Thioglycosides are among the most important glycomimetics …

2-Iodo-1-C-acceptor-substituted glycals: synthesis and transformation into 1, 2-C, C-disubstituted glycals via Suzuki–Miyaura coupling reaction

É Juhász-Tóth, ÁS Malecz, M Tóth, Á Homolya… - New Journal of …, 2023 - pubs.rsc.org
A series of 2-iodo-1-C-substituted glycals having electron withdrawing groups (CN,
CO2CH3, CONH2) at the C-1 carbon were synthesized from the parent 1-C-substituted …

2‐Halo Glycals as “Synthon” for 2‐C‐Branched Sugar: Recent Advances and Applications in Organic Synthesis

N Hussain, A Ahmed… - Asian Journal of Organic …, 2020 - Wiley Online Library
Glycals are unsaturated sugars having an enolic double bond present inside the ring and
act as a versatile synthon for the synthesis of natural products and biologically important …