Molecular catalysts with diphosphine ligands containing pendant amines
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
Considering the Influence of Polymer–Catalyst Interactions on the Chemical Microenvironment of Electrocatalysts for the CO2 Reduction Reaction
Conspectus The electrochemical CO2 reduction reaction (CO2RR) is an attractive method
for capturing intermittent renewable energy sources in chemical bonds, and converting …
for capturing intermittent renewable energy sources in chemical bonds, and converting …
Mechanism of cations suppressing proton diffusion kinetics for electrocatalysis
Proton transfer is crucial for electrocatalysis. Accumulating cations at electrochemical
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …
Synergistic effects of Ni and acid sites for hydrogenation and C–O bond cleavage of substituted phenols
W Song, Y Liu, E Baráth, C Zhao, JA Lercher - Green Chemistry, 2015 - pubs.rsc.org
The cleavage of C–O bonds in phenol, catechol, and guaiacol has been explored with mono-
and dual-functional catalysts containing Ni and/or HZSM-5 in the aqueous phase. The …
and dual-functional catalysts containing Ni and/or HZSM-5 in the aqueous phase. The …
Brønsted–Lowry acid strength of metal hydride and dihydrogen complexes
RH Morris - Chemical Reviews, 2016 - ACS Publications
Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
Graphite-conjugated rhenium catalysts for carbon dioxide reduction
S Oh, JR Gallagher, JT Miller… - Journal of the American …, 2016 - ACS Publications
Condensation of fac-Re (5, 6-diamino-1, 10-phenanthroline)(CO) 3Cl to o-quinone edge
defects on graphitic carbon surfaces generates graphite-conjugated rhenium (GCC-Re) …
defects on graphitic carbon surfaces generates graphite-conjugated rhenium (GCC-Re) …
Hydrogen and dihydrogen bonds in the reactions of metal hydrides
NV Belkova, LM Epstein, OA Filippov… - Chemical …, 2016 - ACS Publications
The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides
RM Bullock, AM Appel, ML Helm - Chemical Communications, 2014 - pubs.rsc.org
Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …
Facile Solvent-Free Synthesis of Thin Iron Porphyrin COFs on Carbon Cloth Electrodes for CO2 Reduction
We demonstrate the solvent-free synthesis of a covalent organic framework (COF)
containing 5, 10, 15, 20-tetra-(4-aminophenyl) porphyrin Fe (III) chloride (FeTAPPCl) and 2 …
containing 5, 10, 15, 20-tetra-(4-aminophenyl) porphyrin Fe (III) chloride (FeTAPPCl) and 2 …
Hydrogen tunneling in enzymes and biomimetic models
JP Layfield, S Hammes-Schiffer - Chemical reviews, 2014 - ACS Publications
Hydrogen transfer reactions play an important role throughout chemistry and biology. In
general, hydrogen transfer reactions encompass proton and hydride transfer, which are …
general, hydrogen transfer reactions encompass proton and hydride transfer, which are …