Theoretical chemical kinetics in tropospheric chemistry: methodologies and applications

L Vereecken, DR Glowacki, MJ Pilling - Chemical reviews, 2015 - ACS Publications
Chemical kinetics is central in much of tropospheric chemistry and in modeling tropospheric
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …

Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact

TA Stephenson, MI Lester - International Reviews in Physical …, 2020 - Taylor & Francis
Criegee intermediates are reactive species formed in the ozonolysis of alkenes. Their
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …

Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor

W Chao, JT Hsieh, CH Chang, JJM Lin - Science, 2015 - science.org
Carbonyl oxides, or Criegee intermediates, are important transient species formed in the
reactions of unsaturated hydrocarbons with ozone. Although direct detection of Criegee …

The physical chemistry of Criegee intermediates in the gas phase

DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …

UV absorption probing of the conformer-dependent reactivity of a Criegee intermediate CH 3 CHOO

L Sheps, AM Scully, K Au - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
We measure the UV absorption spectrum of a Criegee intermediate acetaldehyde oxide,
CH3CHOO, using time-resolved broadband cavity-enhanced spectrometry. We separate the …

[HTML][HTML] Perspective: Spectroscopy and kinetics of small gaseous Criegee intermediates

YP Lee - The Journal of chemical physics, 2015 - pubs.aip.org
The Criegee intermediates, carbonyl oxides proposed by Criegee in 1949 as key
intermediates in the ozonolysis of alkenes, play important roles in many aspects of …

Unimolecular dissociation dynamics of vibrationally activated CH3CHOO Criegee intermediates to OH radical products

NM Kidwell, H Li, X Wang, JM Bowman, MI Lester - Nature Chemistry, 2016 - nature.com
The hydroxyl radical is an important atmospheric oxidant, and a significant source of its
production occurs through alkene ozonolysis. This takes place via a cycloaddition reaction …

A kinetic study of the CH 2 OO Criegee intermediate self-reaction, reaction with SO 2 and unimolecular reaction using cavity ring-down spectroscopy

R Chhantyal-Pun, A Davey, DE Shallcross… - Physical Chemistry …, 2015 - pubs.rsc.org
Criegee intermediates are important species formed during the ozonolysis of alkenes.
Reaction of stabilized Criegee intermediates with various species like SO2 and NO2 may …

The UV absorption spectrum of the simplest Criegee intermediate CH 2 OO

WL Ting, YH Chen, W Chao, MC Smith - Physical Chemistry …, 2014 - pubs.rsc.org
SO2 scavenging and self-reaction of CH2OO were utilized for the decay of CH2OO to extract
the absorption spectrum of CH2OO under bulk conditions. Absolute absorption cross …

Synthesis, electronic spectroscopy, and photochemistry of methacrolein oxide: a four-carbon unsaturated Criegee intermediate from isoprene ozonolysis

MF Vansco, B Marchetti, N Trongsiriwat… - Journal of the …, 2019 - ACS Publications
Ozonolysis of isoprene, one of the most abundant volatile organic compounds in the earth's
atmosphere, generates the four-carbon unsaturated methacrolein oxide (MACR-oxide) …