Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Gold chemistry has developed extensively in the past decade, and a dozen good reviews
have been presented discussing this progress. Few however have paid close attention to …

Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …

In the last decade, major advances have been made in homogeneous gold catalysis.
However, AuI/AuIII catalytic cycle remains much less explored due to the reluctance of AuI to …

Ligand-enabled oxidative addition of Csp2-X bonds to Au (I) centers has recently appeared
as a valuable strategy for the development of catalytic RedOx processes. Several cross …

We describe a AuI complex of a hemi‐labile (C^ N) N‐heterocyclic carbene ligand that is
able to mediate oxidative addition of aryl iodides. Detailed computational and experimental …

Heteroarylation of alkenes with aryl iodides was efficiently achieved with a (MeDalphos)
AuCl complex through AuI/AuIII catalysis. The possibility to combine oxidative addition of …

Exploration of elementary reactions in organometallic catalysis is an important method with
which to discover new reactions. In this article, we report a gold (I)‐catalyzed iodo …

A MeDalPhos-ligated gold (III) metallafluorene complex, generated via C–C oxidative
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …