Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Electrocatalytic hydrogen oxidation in alkaline media: from mechanistic insights to catalyst design

ZC Yao, T Tang, Z Jiang, L Wang, JS Hu, LJ Wan - ACS nano, 2022 - ACS Publications
With the potential to circumvent the need for scarce and cost-prohibitive platinum-based
catalysts in proton-exchange membrane fuel cells, anion-exchange membrane fuel cells …

Understanding Alkaline Hydrogen Oxidation Reaction on PdNiRuIrRh High‐Entropy‐Alloy by Machine Learning Potential

Y Men, D Wu, Y Hu, L Li, P Li, S Jia… - Angewandte Chemie …, 2023 - Wiley Online Library
High‐entropy alloy (HEA) catalysts have been widely studied in electrocatalysis. However,
identifying atomic structure of HEA with complex atomic arrangement is challenging, which …

Unlocking interfacial electron transfer of ruthenium phosphides by homologous core–shell design toward efficient hydrogen evolution and oxidation

H Du, Z Du, T Wang, B Li, S He, K Wang… - Advanced …, 2022 - Wiley Online Library
Developing high‐efficiency electrocatalysts for the hydrogen evolution and oxidation
reactions (HER/HOR) in alkaline electrolytes is of critical importance for realizing renewable …

The Role of Discrepant Reactive Intermediates on Ru‐Ru2P Heterostructure for pH‐Universal Hydrogen Oxidation Reaction

L Su, Y Jin, D Gong, X Ge, W Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Developing highly efficient electrocatalysts for hydrogen oxidation reaction (HOR) under
alkaline media is essential for the commercialization of alkaline exchange membrane fuel …

Electric-double-layer origin of the kinetic pH effect of hydrogen electrocatalysis revealed by a universal hydroxide adsorption-dependent inflection-point behavior

L Su, J Chen, F Yang, P Li, Y Jin, W Luo… - Journal of the American …, 2023 - ACS Publications
The mechanism of the kinetic pH effect in hydrogen electrocatalysis, that is, the order-of-
magnitude kinetic gap between the hydrogen oxidation and evolution reactions (HOR/HER) …

Fast and Durable Alkaline Hydrogen Oxidation Reaction at the Electron‐Deficient Ruthenium–Ruthenium Oxide Interface

X Zhang, L Xia, G Zhao, B Zhang, Y Chen… - Advanced …, 2023 - Wiley Online Library
The slow hydrogen oxidation reaction (HOR) kinetics under alkaline conditions remain a
critical challenge for the practical application of alkaline exchange membrane fuel cells …

Modification of the Intermediate Binding Energies on Ni/Ni3N Heterostructure for Enhanced Alkaline Hydrogen Oxidation Reaction

L Su, D Gong, N Yao, Y Li, Z Li… - Advanced Functional …, 2021 - Wiley Online Library
Developing highly efficient and stable non‐precious metal‐based electrocatalysts for
alkaline hydrogen oxidation reaction (HOR) is essential for the commercialization of alkaline …

Toward the fast and durable alkaline hydrogen oxidation reaction on ruthenium

XB Zhang, X Xiao, J Chen, Y Liu, H Pan… - Energy & …, 2022 - pubs.rsc.org
Anion exchange membrane fuel cells (AEMFCs) are becoming highly attractive for the
efficient utilization of hydrogen energy due to the rapid development of platinum group metal …

Breaking Surface Atomic Monogeneity of Rh2P Nanocatalysts by Defect‐Derived Phosphorus Vacancies for Efficient Alkaline Hydrogen Oxidation

H Huang, K Liu, F Yang, J Cai, S Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Breaking atomic monogeneity of catalyst surfaces is promising for constructing synergistic
active centers to cope with complex multi‐step catalytic reactions. Here, we report a defect …