Electronic coupling and electron transfer in hydrogen-bonded mixed-valence compounds

J Li, Y Shi, T Cheng - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Electron transfer provided by hydrogen bonds represents a unique and highly significant
area of research, as it has a crucial role to play in a wide variety of chemical and biological …

Enhancing the air stability of dimolybdenum paddlewheel complexes: Redox tuning through fluorine substituents

IAZ Squire, CA Goult, BC Thompson… - Inorganic …, 2022 - ACS Publications
The optical and electrochemical properties of quadruply bonded dimolybdenum
paddlewheel complexes (Mo2PWCs) make them ideal candidates for incorporation into …

Experimental and Theoretical Studies on Arene‐Bridged Metal–Metal‐Bonded Dimolybdenum Complexes

M Carrasco, N Curado, E Álvarez… - … A European Journal, 2014 - Wiley Online Library
The bis (hydride) dimolybdenum complex,[Mo2 (H) 2 {HC (N‐2, 6‐iPr2C6H3) 2} 2 (thf) 2], 2,
which possesses a quadruply bonded Mo2II core, undergoes light‐induced (365 nm) …

Effect of Protonation upon Electronic Coupling in the Mixed Valence and Mixed Protonated Complex, [Ni(2,3-pyrazinedithiol)2]

SR Kennedy, P Goyal, MN Kozar… - Inorganic …, 2016 - ACS Publications
We demonstrate that protonation of a mixed valence molecule, generating a mixed valence
mixed protonated (MVMP) state, results in a severe reduction in the electronic coupling …

Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms

BJ Cook, CH Chen, M Pink, KG Caulton - Dalton Transactions, 2018 - pubs.rsc.org
The behavior of the complex (H2L) CoCl2, where H2L is a bis-(pyrazol-3-yl) pyridine,
towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a …

Terphenyl Complexes of Molybdenum and Tungsten with Quadruple Metal–Metal Bonds and Bridging Carboxylate Ligands

M Carrasco, I Mendoza, M Faust… - Journal of the …, 2014 - ACS Publications
Mono-and bis-terphenyl complexes of molybdenum and tungsten with general composition
M2 (Ar′)(O2CR) 3 and M2 (Ar′) 2 (O2CR) 2, respectively (Ar′= terphenyl ligand), that …

Charge-Separated Mixed Valency in an Unsymmetrical Acceptor–Donor–Donor Triad Based on Diarylboryl and Triarylamine Units

K Tahara, H Koyama, M Fujitsuka… - The Journal of …, 2019 - ACS Publications
In this study, we report the generation of new mixed-valence (MV) subspecies with charge-
separated (CS) characters from an unsymmetrical acceptor–donor–donor (A–D–D) triad …

[HTML][HTML] Dimolybdenum (II, II) paddlewheel complexes bearing non-steroidal anti-inflammatory drug ligands: Insights into the chemico-physical profile and first …

L Chiaverini, V Notarstefano, I Tolbatov, P Umari… - Journal of Inorganic …, 2024 - Elsevier
Multinuclear complexes are metal compounds featured by adjacent bound metal centers
that can lead to unconventional reactivity. Some M 2 L 4-type paddlewheel dinuclear …

Ruthenium (II) η6-arene complexes containing a dinucleating ligand based on 1, 8-naphthyridine

WH Tang, YH Liu, SM Peng, ST Liu - Journal of Organometallic Chemistry, 2015 - Elsevier
Abstract Ruthenium arene complexes,[(η 6-p-cymene) 2 Ru 2 (L) Cl 2](PF 6) 2 [3b, L= 2, 7-
bis (di-2-pyridinyl)-1, 8-naphthyridine] and [(η 6-p-cymene) Ru (L′) Cl](PF 6)[4, L′= tri (2 …

Organic mixed valency in quadruple hydrogen-bonded triarylamine dimers bearing ureido pyrimidinedione moieties

K Tahara, T Nakakita, S Katao, J Kikuchi - Chemical Communications, 2014 - pubs.rsc.org
Quadruple hydrogen-bonding interactions stabilized the mixed-valence states of dimers of
triarylamine derivatives bearing an ureido pyrimidinedione moiety without any electronic …