Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Palladium-catalysed cross-coupling reactions constitute a powerful class of chemical
methods for the creation of carbon-carbon and carbon-heteroatom bonds used in organic …

A metal‐free radical borylation of alkyl and aryl iodides with bis (catecholato) diboron
(B2cat2) as the boron source under mild conditions is introduced. The borylation reaction is …

We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …

Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a
major challenge still remains: very few boron-centered nucleophiles exist for the direct …

A pyridine-catalyzed transition-metal-free borylation reaction of haloarenes has been
developed based on the selective cross-coupling of an aryl radical and a pyridine-stabilized …