The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

Transition metal-catalyzed C–H bond functionalizations have been the focus of intensive
research over the last decades for the formation of C–C bonds from unfunctionalized arenes …

Biaryl scaffolds are found in natural products and drug molecules and exhibit a wide range
of biological activities. In past decade, the transition metal-catalyzed C–H arylation reaction …

Conspectus Introducing aryl-and heteroaryl moieties into molecular scaffolds are often key
steps in the syntheses of natural products, drugs, or functional materials. A variety of cross …

Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

A broadly applicable copper catalyst for photoredox transformations of organic halides is
reported. Upon visible light irradiation in the presence of catalytic amounts of …

Abstract Photocatalytic selective C (sp3)–H activation/cross-coupling reactions are
appealing in organic synthesis. In this manuscript, we describe the development of …

Conspectus Over the past decade, photoredox catalysis has blossomed as a powerful
methodology because of its wide applicability in sustainable free-radical-mediated …

The first example of near-room-temperature α-arylation of benzo [b] thiophenes is reported.
The discovery rests on the observation of a switch in α-/β-regioselectivity at different …

A visible-light-induced photocatalytic method for the arylsulfonylation of heterocycles has
been developed. The synthetic utility of this reaction is reflected by the direct use of …