The selective functionalization of carbohydrates holds a central position in synthetic
carbohydrate chemistry, driving the ongoing quest for ideal approaches to manipulate these …

C-Glycosides are essential for the study of biological processes and the development of
carbohydrate-based drugs. Despite the tremendous hurdles, glycochemists have often …

Radical C-glycosylation presents a flexible and efficient method for synthesizing C-
glycosides. Existing methods always require multistep processes for generating anomeric …

An efficient and practical glycosylation platform for synthesizing N-glycosides by leveraging
palladium catalysis is disclosed. This approach enables facile access to diverse heterocyclic …

Abstract gem‐Diborylalkanes are highly valuable building blocks in organic synthesis and
pharmaceutical chemistry due to their ability to participate in multi‐step cross‐coupling …

Previous N‐glycosylation approaches have predominately involved acidic conditions, facing
challenges of low stereoselectivity and limited scope. Herein, we introduce a radical …

The glycosylation of peptides and proteins can significantly impact their intrinsic properties,
such as conformation, stability, antigenicity, and immunogenicity. Current methods for …

Chemical N-glycoconjugation can provide a unique way to tailor the properties of the
ubiquitous amines for further expending their diverse functions and applications …

A systematic radical polarity analysis framework is formulated herein for the projection of
radical reactivity patterns. An iodine (III)-mediated photochemical C–H azolation reaction …

Transition metal catalysis has long been recognized as one of the most important tools for
the construction of carbon-carbon bond and carbon-heteroatom bonds in modern organic …