Carbenes (R2C:), compounds with a divalent carbon atom containing only six valence shell
electrons, have evolved into a broader class with the replacement of the carbene carbon or …

Cyclic structures represent a well-studied structural class due to the novel bonding modes
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …

A series of new germylene compounds has been synthesized offering systematic variation in
the σ‐and π‐capabilities of the α‐substituent and differing levels of reactivity towards E− H …

The synthesis of a bicyclic germylene from the reaction of a germole dianion with hafnocene
dichloride is reported. This germylene is stabilized by a homoconjugative interaction of the …

The substituent effect of different p-substituted triphenylsilyl chlorides on silylation-based
kinetic resolutions was explored. Electron-donating groups slow down the reaction rate and …

The extremely bulky N‐heterocyclic carbene (NHC), ITr (ITr=[(HCNCPh3) 2C:]) featuring
sterically shielding umbrella‐shaped trityl (CPh3) substituents was prepared. This NHC …

The use of bulky aryl (silyl) amides (R) as substituents for the stabilisation of phospha‐
germynes and phospha‐stannynes (R− Ge≡ P and R− Sn≡ P, respectively) is described …

This study details the syntheses of N-heterocyclic germylenes and stannylenes featuring
diazaborolyl groups,{(HCDippN) 2B}(Dipp= 2, 6-iPr2C6H3), as both of the N-bound …

New 10π-electron stabilized O, N-heterocyclic germylene was synthesized and structurally
characterized for the first time. Its reduction with potassium in THF resulted in a unique low …

A 1, 4-addition of a dichlorogermylene dioxane complex with α, β-unsaturated imine 1 gave
a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing …