Extremely rapid polythioether synthesis in the presence of TBD

O Daglar, US Gunay, G Hizal, U Tunca… - Macromolecules, 2019 - ACS Publications
A straightforward, novel, and extremely rapid method is developed for the synthesis of
polythioether based on the reaction of dimethyl acetylenedicarboxylate with electron …

Ultrafast synthesis of phosphorus-containing polythioethers in the presence of TBD

O Daglar, B Alkan, US Gunay, G Hizal, U Tunca… - European Polymer …, 2022 - Elsevier
Phosphorus-based polymers have gained much interest in recent years due to the
phosphorus atoms that impart polymers interesting properties. Thus, the synthesis of …

Extremely rapid postfunctionalization of maleate and fumarate main chain polyesters in the presence of TBD

O Daglar, B Ozcan, US Gunay, G Hizal, U Tunca… - Polymer, 2019 - Elsevier
Unsaturated polyester (UP) scaffold, poly (butylene maleate)(P1), possessing an electron-
deficient double bond in the main chain was prepared and utilized as a precursor for thiol …

Mechanisms of Alkyl and Aryl Thiol Addition to N-Methylmaleimide

MAR Raycroft, KE Racine, CN Rowley… - The Journal of Organic …, 2018 - ACS Publications
A mechanistic study was undertaken to elucidate the reaction pathways for thiol addition to
N-methylmaleimide in water. We used linear free energy relationships, solvent kinetic …

Reversible regulation of thermoresponsive property of dithiomaleimide-containing copolymers via sequential thiol exchange reactions

Z Tang, P Wilson, K Kempe, H Chen… - ACS Macro …, 2016 - ACS Publications
The facile and efficient functionalization of thermoresponsive polymers based on sequential,
reversible thiol-exchange reactions is reported. Well-defined dithiomaleimide-containing …

Rapid polythioether synthesis and thioether network formation using thiol-yne chemistry of electron-deficient alkynes

US Gunay, U Tunca, H Durmaz - Journal of Macromolecular …, 2024 - Taylor & Francis
The preparation of polythioethers has gained importance again after the development of
click chemistry reactions. The thiol-X reactions, ie, thiol-ene reactions based on free radical …

[PDF][PDF] Extremely rapid synthesis of polymers and post-polymerization modifications via novel and straightforward methods

Ö Dağlar - 2020 - polen.itu.edu.tr
Modifications at the macromolecular level, which result from the adaptation of developments
in organic chemistry to polymer chemistry, allow polymer chemistry to develop very rapidly …

[PDF][PDF] Extremely rapid postfunctionalization of polyesters in the presence of TBD

B Özcan - 2020 - polen.itu.edu.tr
Unsaturated polyesters (UP) as commercially important polymers have been used
remarkably for wide range applications due to their double bond nature provides a site for …