Photo-and redox-driven artificial molecular motors

M Baroncini, S Silvi, A Credi - Chemical reviews, 2019 - ACS Publications
Directed motion at the nanoscale is a central attribute of life, and chemically driven motor
proteins are nature's choice to accomplish it. Motivated and inspired by such …

The story of the little blue box: a tribute to Siegfried Hünig

XY Chen, H Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …

Radical-pairing-induced molecular assembly and motion

K Cai, L Zhang, RD Astumian, JF Stoddart - Nature Reviews Chemistry, 2021 - nature.com
Radical-pairing interactions between conjugated organic π-radicals are relative newcomers
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …

Selective Extraction of C70 by a Tetragonal Prismatic Porphyrin Cage

Y Shi, K Cai, H Xiao, Z Liu, J Zhou, D Shen… - Journal of the …, 2018 - ACS Publications
Along with the advent of supramolecular chemistry, research on fullerene receptors based
on noncovalent bonding interactions has attracted a lot of attention. Here, we present the …

C (sp3) atoms as tetrel bond donors: A crystallographic survey

A Daolio, P Scilabra, G Terraneo, G Resnati - Coordination Chemistry …, 2020 - Elsevier
The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …

Mechanical-Bond-Induced exciplex fluorescence in an Anthracene-Based homo [2] catenane

A Garci, Y Beldjoudi, MS Kodaimati… - Journal of the …, 2020 - ACS Publications
Collisional intermolecular interactions between excited states form short-lived dimers and
complexes that lead to the emergence of excimer/exciplex emission of lower energy, a …

Molecular Russian dolls

K Cai, MC Lipke, Z Liu, J Nelson, T Cheng, Y Shi… - Nature …, 2018 - nature.com
The host-guest recognition between two macrocycles to form hierarchical non-intertwined
ring-in-ring assemblies remains an interesting and challenging target in noncovalent …

The flowering of mechanically interlocked molecules: Novel approaches to the synthesis of rotaxanes and catenanes

BT Shahraki, S Maghsoudi, Y Fatahi, N Rabiee… - Coordination Chemistry …, 2020 - Elsevier
Since the emergence of mechanical bonds, considerable research efforts have been
devoted to the construction of mechanically interlocked molecules (MIMs), including …

Synthesis and Properties of 1-Azapyrenes

A Vardanyan, S Boldt, A Villinger… - The Journal of …, 2022 - ACS Publications
A straightforward method for the synthesis of a series of hitherto unknown 1-azapyrenes is
reported, which relies on a combination of Pd-catalyzed cross-coupling reactions with …

Synthesis of 2-Azapyrenes and Their Photophysical and Electrochemical Properties

R Molenda, S Boldt, A Villinger, P Ehlers… - The Journal of Organic …, 2020 - ACS Publications
A series of 5, 7, 9-substituted 2-azapyrenes were synthesized for the first time. The synthesis
relies on Brønsted acid promoted benzannulation of alkyne precursors prepared by …