Synthesis, structures and magnetic studies of hexanuclear lanthanide complexes: SMM behavior of the Dy III analogue and MCE properties of the Gd III analogue

P Kumar, P Kalita, MA Palacios, V Kumar… - Dalton …, 2023 - pubs.rsc.org
The synthesis, structure and magnetic properties of homometallic hexanuclear lanthanide
complexes [Ln6 (HL) 4 (tfa) 4 (S) 2]· 2NO3· x H2O· yMeOH (1, Ln= Gd, S= MeOH, x= 0, y= 0; …

Synthesis, structure, magnetic properties and thermal behaviour of Ba–M II (M II= Mn, Co, Cu, and Zn) allylmalonates

EN Zorina-Tikhonova, AK Matyukhina… - New Journal of …, 2022 - pubs.rsc.org
A series of Ba–MII complexes with allylmalonic acid anions (Amal)[BaMII (Amal) 2 (H2O) 3] n
(MII= Mn (1), Co (2), Cu (3), and Zn (4)) were synthesized by the reaction of the …

Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting

EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …

Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold (I) atoms in 2D {Co (L) 2 [Au (CN) 2] 2} n metal–organic …

MA Palacios, IF Díaz-Ortega, H Nojiri… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The assembly of a Co (II) salt with two [Au (CN) 2]− anions and ancillary ligands L afforded
2D complexes of the general formula {Co (L) 2 [Au (CN) 2] 2} n (where L= DMSO (1), DMF …

Field-Induced Slow Magnetic Relaxation in CoII Cyclopropane-1,1-dicarboxylates

AK Matyukhina, EN Zorina-Tikhonova, AS Goloveshkin… - Molecules, 2022 - mdpi.com
New CoII substituted malonate field-induced molecular magnets {[Rb6Co3 (cpdc) 6 (H2O)
12]∙ 6H2O} n (1) and [Cs2Co (cpdc) 2 (H2O) 6] n (2)(where cpdc2− stands for cyclopropane …

Change in the electronic structure of the cobalt (II) ion in a one-dimensional polymer with flexible linkers induced by a structural phase transition

DS Yambulatov, JK Voronina, AS Goloveshkin… - International Journal of …, 2022 - mdpi.com
A new 1D-coordination polymer [Co (Piv) 2 (NH2 (CH2) 6NH2)] n (1, Piv is Me3CCO2−
anion) was obtained, the mononuclear fragments {Co (O2CR) 2} within which are linked by …

Six‐Coordinated CoII Single‐Molecule Magnets: Synthetic Strategy, Structure and Magnetic Properties

M Wang, Z Han, Y Garcia, P Cheng - ChemPhysChem, 2024 - Wiley Online Library
The pursuit of molecule‐based magnetic memory materials contributes significantly to high‐
density information storage research in the frame of the ongoing information technologies …

Fine-Tuning of Uniaxial Anisotropy and Slow Relaxation of Magnetization in the Hexacoordinate Co (II) Complexes with Acidoligands

YP Tupolova, IN Shcherbakov… - The Journal of …, 2020 - ACS Publications
A new hexacoordinate Co (II) complex with the general formula [CoL (NCS) 2]· DMSO (1)(L=
biscondensation product of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine, DMSO …

Layered uranyl phosphonates encapsulating Co (II)/Mn (II)/Zn (II) ions: Exfoliation into nanosheets and its impact on magnetic and luminescent properties

GH Wen, Q Zou, K Xu, XD Huang… - … A European Journal, 2022 - Wiley Online Library
Layered heterometallic 5f–3d uranyl phosphonates can exhibit unique luminescent and/or
magnetic properties, but the fabrication and properties of their 2D counterparts have not …

Field-induced single-ion magnet based on a quasi-octahedral Co (II) complex with mixed sulfur–oxygen coordination environment

DV Korchagin, YE Gureev, EA Yureva, GV Shilov… - Dalton …, 2021 - pubs.rsc.org
Synthesis and characterization of structure and magnetic properties of the quasi-octahedral
complex (pipH2)[Co (TDA) 2] 2H2O (I),(pipH22+= piperazine dication, TDA2−= thiodiacetic …