Electrochemical transformations catalyzed by cytochrome P450s and peroxidases

N Kumar, J He, JF Rusling - Chemical Society Reviews, 2023 - pubs.rsc.org
Cytochrome P450s (Cyt P450s) and peroxidases are enzymes featuring iron heme cofactors
that have wide applicability as biocatalysts in chemical syntheses. Cyt P450s are a family of …

Are supercritical fluids solvents for the future?

Ž Knez, M Pantić, D Cör, Z Novak, MK Hrnčič - Chemical Engineering and …, 2019 - Elsevier
High pressure technologies involving sub and supercritical fluids offer the possibility to
obtain new products with special characteristics or to design new processes which are …

Getting the Most Out of Enzyme Cascades: Strategies to Optimize In Vitro Multi-Enzymatic Reactions

R Siedentop, C Claaßen, D Rother, S Lütz… - Catalysts, 2021 - mdpi.com
In vitro enzyme cascades possess great benefits, such as their synthetic capabilities for
complex molecules, no need for intermediate isolation, and the shift of unfavorable equilibria …

Immobilized laccase in the form of (magnetic) cross-linked enzyme aggregates for sustainable diclofenac (bio) degradation

M Primožič, G Kravanja, Ž Knez, A Crnjac… - Journal of Cleaner …, 2020 - Elsevier
Nowadays, major problems worldwide derive from the presence of pharmaceutically active
compounds in the wastewater of hospitals and healthcare facilities. To address this issue …

Ionic liquids as a potential solvent for lipase-catalysed reactions: A review

AA Elgharbawy, FA Riyadi, MZ Alam… - Journal of Molecular …, 2018 - Elsevier
Ionic liquids (ILs)-as environmentally friendly “green” solvents-have been progressively
used in various reactions as reagents, solvents and co-solvents including lipase-catalysed …

Enzyme hydration determines resistance in organic cosolvents

H Cui, L Zhang, L Eltoukhy, Q Jiang, SK Korkunç… - ACS …, 2020 - ACS Publications
Biocatalysis in organic solvents (OSs) has found various important applications, particularly
in organic synthesis and for the production of pharmaceuticals, flavors, and fragrances …

What do we learn from enzyme behaviors in organic solvents?–Structural functionalization of ionic liquids for enzyme activation and stabilization

H Zhao - Biotechnology Advances, 2020 - Elsevier
Enzyme activity in nonaqueous media (eg conventional organic solvents) is typically lower
than in water by several orders of magnitude. There is a rising interest of developing new …

Recent advances of enzymatic reactions in ionic liquids: Part II

AAM Elgharbawy, M Moniruzzaman, M Goto - Biochemical Engineering …, 2020 - Elsevier
As a biocompatible and designer solvents, ionic liquids (ILs) are extensively used for
enzymatic conversion of substrates, particularly those that are insoluble or sparingly soluble …

Deep eutectic solvents for enzymatic esterification of racemic menthol

R Craveiro, L Meneses, L Durazzo… - ACS Sustainable …, 2019 - ACS Publications
Enzymatic esterification is an effective route that can contribute for the separation of racemic
(rac) mixtures and is thus of great importance for the pharmaceutical, food, and cosmetic …

Stimulus‐responsive regulation of enzyme activity for one‐step and multi‐step syntheses

C Claaßen, T Gerlach, D Rother - Advanced synthesis & …, 2019 - Wiley Online Library
Multi‐step biocatalytic reactions have gained increasing importance in recent years because
the combination of different enzymes enables the synthesis of a broad variety of industrially …