Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
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Catalytic reactions promoted by N-heterocyclic carbenes (NHCs) have exploded in
popularity since 2004 when several reports described new fundamental reactions that …

First reported less than a decade ago, the α, β-unsaturated acyl azolium has emerged as a
central reactive intermediate for reaction discovery using N-heterocyclic carbene catalysis …

This Concept article discusses the potential of oxidative carbene catalysis in synthesis and
comprehensively covers pioneering studies as well as recent developments. Oxidative …

The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

Organocatalysis represents a synthetic paradigm that has grown exponentially in popularity
over the last decade, arguably becoming one of the most desired synthetic methods for the …

The secondary amine‐catalyzed reactions proceeding via α, β‐unsaturated iminiums and
the N‐heterocyclic carbene (NHC)‐catalyzed transformations taking place via α, β …

N‐Heterocyclic carbene (NHC) catalysis is a by now consolidated organocatalytic platform
for a number of synthetic (asymmetric) transformations via diverse reaction …

The combination of N-heterocyclic carbene (NHC) catalysts with α, β-unsaturated aldehydes
has emerged as one of the most powerful methods for enantioselective CÀC bond forming …

Biomass photorefinery is an ideal concept to help alleviate the current energy crisis and
move toward carbon neutrality. Nevertheless, limited by the complex structure and multiple …