Organocatalytic reactions enabled by N-heterocyclic carbenes
DM Flanigan, F Romanov-Michailidis, NA White… - Chemical …, 2015 - ACS Publications
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
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On the mechanism of N-heterocyclic carbene-catalyzed reactions involving acyl azoliums
J Mahatthananchai, JW Bode - Accounts of chemical research, 2014 - ACS Publications
Catalytic reactions promoted by N-heterocyclic carbenes (NHCs) have exploded in
popularity since 2004 when several reports described new fundamental reactions that …
popularity since 2004 when several reports described new fundamental reactions that …
N-Heterocyclic Carbene Catalysis via the α,β-Unsaturated Acyl Azolium
First reported less than a decade ago, the α, β-unsaturated acyl azolium has emerged as a
central reactive intermediate for reaction discovery using N-heterocyclic carbene catalysis …
central reactive intermediate for reaction discovery using N-heterocyclic carbene catalysis …
Catalysis with N‐heterocyclic carbenes under oxidative conditions
S De Sarkar, A Biswas, RC Samanta… - … –A European Journal, 2013 - Wiley Online Library
This Concept article discusses the potential of oxidative carbene catalysis in synthesis and
comprehensively covers pioneering studies as well as recent developments. Oxidative …
comprehensively covers pioneering studies as well as recent developments. Oxidative …
New developments of the principle of vinylogy as applied to π-extended enolate-type donor systems
The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …
are possibly transmitted to a distal position through interposed conjugated multiple bonds …
NHCs in asymmetric organocatalysis: recent advances in azolium enolate generation and reactivity
Organocatalysis represents a synthetic paradigm that has grown exponentially in popularity
over the last decade, arguably becoming one of the most desired synthetic methods for the …
over the last decade, arguably becoming one of the most desired synthetic methods for the …
Revealing the similarities of α, β‐unsaturated iminiums and acylazoliums in organocatalysis
The secondary amine‐catalyzed reactions proceeding via α, β‐unsaturated iminiums and
the N‐heterocyclic carbene (NHC)‐catalyzed transformations taking place via α, β …
the N‐heterocyclic carbene (NHC)‐catalyzed transformations taking place via α, β …
Oxidative N‐Heterocyclic Carbene Catalysis
C De Risi, A Brandolese, G Di Carmine… - … A European Journal, 2023 - Wiley Online Library
N‐Heterocyclic carbene (NHC) catalysis is a by now consolidated organocatalytic platform
for a number of synthetic (asymmetric) transformations via diverse reaction …
for a number of synthetic (asymmetric) transformations via diverse reaction …
Enantioselective, NHC‐Catalyzed Annulations of Trisubstituted Enals and Cyclic N‐Sulfonylimines via α,β‐Unsaturated Acyl Azoliums
AG Kravina, J Mahatthananchai… - Angewandte Chemie …, 2012 - Wiley Online Library
The combination of N-heterocyclic carbene (NHC) catalysts with α, β-unsaturated aldehydes
has emerged as one of the most powerful methods for enantioselective CÀC bond forming …
has emerged as one of the most powerful methods for enantioselective CÀC bond forming …
Selective C3–C4 cleavage via glucose photoreforming under the effect of nucleophilic dimethyl sulfoxide
Biomass photorefinery is an ideal concept to help alleviate the current energy crisis and
move toward carbon neutrality. Nevertheless, limited by the complex structure and multiple …
move toward carbon neutrality. Nevertheless, limited by the complex structure and multiple …