The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

Conspectus Benzo-fused skeletons are ubiquitous in agrochemicals, medicines, natural
products, catalysts, and other organic function materials. The assembly of these skeletons in …

Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

Due to the intrinsic inertness of alkanes, strong oxidative conditions are typically required to
enable their C (sp3)− H functionalization. Herein, a paired electrocatalysis strategy was …

Tri-and tetrasubstituted olefins are widely present in biologically active molecules and
functional materials. However, the methods for the stereoselective construction of such …

Methods that can simultaneously install multiple different functional groups to heteroarenes
via C− H functionalizations are valuable for complex molecule synthesis, which, however …

In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Aromatic amines are ubiquitous moieties in organic molecules and their direct
functionalization is of great interest in many research areas due to their prevalence in …