Copper-catalyzed oxidative cyclization of 1, 5-enynes with concomitant C–C bond cleavage: an unexpected access to 3-formyl-1-indenone derivatives

J Zhang, D Wu, X Chen, Y Liu, Z Xu - The Journal of Organic …, 2014 - ACS Publications
A Cu (0)/Selectfluor system-mediated oxidative cyclization of 1, 5-enynes with concomitant C–
C bond cleavage to access 3-formyl-1-indenone derivatives is described. Preliminary …

Non-Innocent Behavior of Substrate Backbone Esters in Metal-Catalyzed Carbocyclizations and Friedel–Crafts Reactions of Enynes and Arenynes

B Michelet, G Thiery, C Bour… - The Journal of Organic …, 2015 - ACS Publications
On the basis of DFT computations and experimental results, we show that the presence of
the ester group in the backbone of organic substrates can influence the mechanism of metal …

Platinum (ii)–phosphole complexes: synthesis and evaluation as enyne cycloisomerisation catalysts

K Fourmy, S Mallet-Ladeira, O Dechy-Cabaret… - Dalton …, 2014 - pubs.rsc.org
A series of platinum (II)–monophosphole complexes has been synthesized and used in
enyne cycloisomerisations in order to study the effect of the ligand on the catalytic activity …

Ene‐Yne Metathesis

ST Diver, JR Griffiths - Olefin metathesis: theory and practice, 2014 - Wiley Online Library
Ene‐yne metathesis is the carbon‐carbon bond coupling that occurs between an alkene
and an alkyne with pi bond reorganization. By far the most common use of ene‐yne …

Gold (I) complexes bearing P‐pyrrole phosphine ligands: Synthesis and catalytic activity towards cycloisomerization of 1, 6‐enynes

EP Sánchez‐Rodríguez… - Applied …, 2020 - Wiley Online Library
P‐pyrrole phosphines (R2Ppyr), in which a pyrrole group is directly bonded to the
phosphorus atom, act as monodentate k‐P ligands towards gold (I) center to afford either …

Palladium-catalyzed cycloisomerisation reaction of 1, 6-enyne acetic esters to form five-membered nitrogenated heterocyclic conjugated trienes

T He, P Gao, S Fang, Y Chi, Y Chen - Tetrahedron Letters, 2017 - Elsevier
A palladium-catalyzed cycloisomerisation reaction of 1, 6-enyne acetic esters have been
developed. This cyclization reaction shows excellent regioselectivity and good functional …

Catalytic Rearrangements and Allylation Reactions in Water

V Cadierno, J García‐Álvarez… - … Reactions in Water, 2013 - Wiley Online Library
Catalytic Rearrangements and Allylation Reactions in Water Page 1 243 7 Catalytic
Rearrangements and Allylation Reactions in Water Victorio Cadierno, Joaquın Garcıa-Álvarez …