Formic acid‐based liquid organic hydrogen carrier system with heterogeneous catalysts

H Zhong, M Iguchi, M Chatterjee… - Advanced …, 2018 - Wiley Online Library
Formic acid (HCOOH), with a hydrogen capacity of 4.3 wt%, has attracted increasing interest
in the utilization as a promising H2 carrier. The CO2 HCOOH cycle is believed to be a …

Metal-support interactions in heterogeneous catalytic hydrogen production of formic acid

S Bai, A Jia, J Song, S Cao, N Wang, X Liu - Chemical Engineering Journal, 2023 - Elsevier
Hydrogen (H 2) is regarded as a novel energy carrier with huge development potential, and
it will be essential in future clean energy systems. Given the existing challenges in direct H 2 …

Recent advances in catalytic transfer hydrogenation with formic acid over heterogeneous transition metal catalysts

R Nie, Y Tao, Y Nie, T Lu, J Wang, Y Zhang, X Lu… - ACS …, 2021 - ACS Publications
Transition-metal-catalyzed transfer hydrogenation with an in situ hydrogen donor has
received a great deal of attention from both academia and industry as an alternative to the …

Catalysis in liquid organic hydrogen storage: recent advances, challenges, and perspectives

MS Salman, N Rambhujun, C Pratthana… - Industrial & …, 2022 - ACS Publications
With the renewed interest for hydrogen as an energy carrier, means to produce, but most
importantly store, transport, and distribute,“green” hydrogen over long distances has …

Functionalized biochars as supports for Pd/C catalysts for efficient hydrogen production from formic acid

JL Santos, C Megías-Sayago, S Ivanova… - Applied Catalysis B …, 2021 - Elsevier
Biomass waste product was used to generate biochars as catalytic supports for selective
hydrogen production from formic acid. The supports were obtained after pyrolysis in CO 2 …

Size-dependent catalytic activity over carbon-supported palladium nanoparticles in dehydrogenation of formic acid

J Li, W Chen, H Zhao, X Zheng, L Wu, H Pan, J Zhu… - Journal of catalysis, 2017 - Elsevier
Hydrogen generation from formic acid (FA) under mild conditions has received significant
attention, where Pd-based catalysts have been widely employed due to their superior …

Understanding the effect of Pd size on formic acid dehydrogenation via size-controlled Pd/C catalysts prepared by NaBH4 treatment

Y Kim, DH Kim - Applied Catalysis B: Environmental, 2019 - Elsevier
Herein, we investigated the effect of Pd size on a formic acid dehydrogenation (FAD)
reaction. A series of size-controlled Pd/C catalysts was simply prepared by a treatment using …

New approaches toward the hydrogen production from formic acid dehydrogenation over Pd-based heterogeneous catalysts

M Navlani-García, K Mori, D Salinas-Torres… - Frontiers in …, 2019 - frontiersin.org
The urgency for finding clean energy sources is nowadays latent, and the role of hydrogen
in the future of energy is well-recognized. However, there are still various barriers that limit …

Mechanistic analysis-guided Pd-based catalysts for efficient hydrogen production from formic acid dehydrogenation

X Qin, H Li, S Xie, K Li, T Jiang, XY Ma, K Jiang… - ACS …, 2020 - ACS Publications
Heterogeneous catalysis of formic acid dehydrogenation at room temperature is a promising
tactic for safely storing and producing H2 as an efficient energy carrier. Up to now, the …

Heterogeneous catalysts for hydrogenation of CO2 and bicarbonates to formic acid and formates

DA Bulushev, JRH Ross - Catalysis Reviews, 2018 - Taylor & Francis
Formic acid and formates are often produced by hydrogenation of CO2 with hydrogen over
homogeneous catalysts. The present review reports recent achievements in utilization of …