Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions
Y Yang, T Mu - Green Chemistry, 2021 - pubs.rsc.org
Electrochemical conversion is emerging as a powerful and promising method to produce a
wide range of high-value chemicals on account of mild operation conditions, controllable …
wide range of high-value chemicals on account of mild operation conditions, controllable …
Electrocatalytic hydrogenation of biomass-derived organics: a review
Sustainable energy generation calls for a shift away from centralized, high-temperature,
energy-intensive processes to decentralized, low-temperature conversions that can be …
energy-intensive processes to decentralized, low-temperature conversions that can be …
Developing electrochemical hydrogenation towards industrial application
JT Kleinhaus, J Wolf, K Pellumbi, L Wickert… - Chemical Society …, 2023 - pubs.rsc.org
Electrochemical hydrogenation reactions gained significant attention as a sustainable and
efficient alternative to conventional thermocatalytic hydrogenations. This tutorial review …
efficient alternative to conventional thermocatalytic hydrogenations. This tutorial review …
Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation
In aqueous mediums, the chemical environment for catalytic reactions is not only comprised
of water molecules but also of corresponding ionized species, ie, hydronium ions, which can …
of water molecules but also of corresponding ionized species, ie, hydronium ions, which can …
Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium
Solvents not only disperse reactants to enhance mass transport in catalytic reactions but
also alter the reaction kinetically. Here, we show that the rate of benzaldehyde …
also alter the reaction kinetically. Here, we show that the rate of benzaldehyde …
Electrochemical Hydrogenation of Furfural in Aqueous Acetic Acid Media with Enhanced 2‐Methylfuran Selectivity Using CuPd Bimetallic Catalysts
Herein, we report a series of CuPd catalysts for electrochemical hydrogenation (ECH) of
furfural to 2‐methylfuran (MF or FurCH3 where Fur= furyl) in aqueous 0.1 M acetic acid (pH …
furfural to 2‐methylfuran (MF or FurCH3 where Fur= furyl) in aqueous 0.1 M acetic acid (pH …
Efficient Electrochemical Hydrogenation of Nitroaromatics into Arylamines on a CuCo2O4 Spinel Cathode in an Alkaline Electrolyte
S Wu, X Huang, H Zhang, Z Wei, M Wang - ACS Catalysis, 2021 - ACS Publications
Establishing an efficient hydrogenation strategy, especially with the use of water as a clean
and safe hydrogen source to synthesize aromatic amines is of significance in the production …
and safe hydrogen source to synthesize aromatic amines is of significance in the production …
Boosting selective hydrogenation through hydrogen spillover on supported-metal catalysts at room temperature
Highly efficient hydrogenation of substrates with strong absorption on metals at low
temperatures is a long-term pursuit. However, due to the scaling relationship of high binding …
temperatures is a long-term pursuit. However, due to the scaling relationship of high binding …
Selectivity origin of organic electrosynthesis controlled by electrode materials: a case study on pinacols
Unveiling the origin of an electrode's ability to control the reaction outcome and identifying
key factors to explore a promising electrode for selective synthesis of value-added …
key factors to explore a promising electrode for selective synthesis of value-added …