Water electrolysis

AJ Shih, MCO Monteiro, F Dattila, D Pavesi… - Nature Reviews …, 2022 - nature.com
Electrochemistry has the potential to sustainably transform molecules with electrons
supplied by renewable electricity. It is one of many solutions towards a more circular …

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Y Li, N Wang, H Lei, X Li, H Zheng, H Wang… - Coordination Chemistry …, 2021 - Elsevier
Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …

Unraveling a bifunctional mechanism for methanol-to-formate electro-oxidation on nickel-based hydroxides

B Zhu, B Dong, F Wang, Q Yang, Y He, C Zhang… - Nature …, 2023 - nature.com
For nickel-based catalysts, in-situ formed nickel oxyhydroxide has been generally believed
as the origin for anodic biomass electro-oxidations. However, rationally understanding the …

Mechanism of oxygen evolution catalyzed by cobalt oxyhydroxide: cobalt superoxide species as a key intermediate and dioxygen release as a rate-determining step

A Moysiadou, S Lee, CS Hsu, HM Chen… - Journal of the American …, 2020 - ACS Publications
The oxygen evolution reaction (OER) is the performance-limiting half reaction of water
splitting, which can be used to produce hydrogen fuel using renewable energies. Whereas a …

Insights into the Low Overpotential Electroreduction of CO2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer

S Verma, Y Hamasaki, C Kim, W Huang, S Lu… - ACS Energy …, 2017 - ACS Publications
Cost competitive electroreduction of CO2 to CO requires electrochemical systems that
exhibit partial current density (j CO) exceeding 150 mA cm–2 at cell overpotentials (| ηcell|) …

Activating lattice oxygen in NiFe-based (oxy) hydroxide for water electrolysis

Z He, J Zhang, Z Gong, H Lei, D Zhou, N Zhang… - Nature …, 2022 - nature.com
Transition metal oxides or (oxy) hydroxides have been intensively investigated as promising
electrocatalysts for energy and environmental applications. Oxygen in the lattice was …

Ferrocene‐based metal–organic framework nanosheets as a robust oxygen evolution catalyst

J Liang, X Gao, B Guo, Y Ding, J Yan… - Angewandte Chemie …, 2021 - Wiley Online Library
We report the synthesis of two‐dimensional metal–organic frameworks (MOFs) on nickel
foam (NF) by assembling nickel chloride hexahydrate and 1, 1′‐ferrocenedicarboxylic acid …

Inverse kinetic isotope effects in the oxygen reduction reaction at platinum single crystals

Y Yang, RG Agarwal, P Hutchison, R Rizo… - Nature Chemistry, 2023 - nature.com
Although the oxygen reduction reaction (ORR) involves multiple proton-coupled electron
transfer processes, early studies reported the absence of kinetic isotope effects (KIEs) on …

Mechanisms of two-electron and four-electron electrochemical oxygen reduction reactions at nitrogen-doped reduced graphene oxide

HW Kim, VJ Bukas, H Park, S Park… - ACS …, 2019 - ACS Publications
Doped carbon-based systems have been extensively studied over the past decade as active
electrocatalysts for both the two-electron (2e–) and four-electron (4e–) oxygen reduction …

Hybrids of cobalt/iron phosphides derived from bimetal–organic frameworks as highly efficient electrocatalysts for oxygen evolution reaction

T Zhang, J Du, P Xi, C Xu - ACS applied materials & interfaces, 2017 - ACS Publications
The electrochemical splitting of water, as an efficient and large-scale method to produce H2,
is still hindered by the sluggish kinetics of the oxygen evolution reaction (OER) at the anode …