The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Hydroboration of alkynes is of special interest to researchers since it is the most
straightforward process for the synthesis of highly important vinylborane synthetic …

This review highlights the hydroelementation reactions of conjugated and separated diynes,
which depending on the process conditions, catalytic system, as well as the type of reagents …

Herein, we describe the functionalization of silylacetylenes with hydroboranes catalyzed by
cobalt (pre) catalysts. The direction of the reaction is determined depending on the type of …

Almost 20 million tons of solvents are released in the nature per year. Solvents represent
about 80% of the total volume of chemicals employed in chemical synthesis. Solvents are …

The mechanism of R2BH-catalyzed hydroboration of alkynes by 1, 3, 2-dioxaborolanes has
been investigated by in situ 19F NMR spectroscopy, kinetic simulation, isotope entrainment …

The first commercially available scandium-catalysed selective hydroboration of alkynes and
alkenes with HBpin (pin= OC-Me2CMe2O) in the presence of a catalytic amount of NaHBEt3 …

Hydrosilylation of borylalkynes to borylsilylalkenes (with a different arrangement of
substituents) has been successfully developed. The cis-addition of SiH group to the CC …

The structurally defined Fe–H complex FeH (CO)(NO)(Ph3P) 2 catalyzes the efficient
stereoselective hydroboration of a variety of internal alkynes using either pinacolborane …

An efficient, simple, metal and ligand free, regioselective hydroboration of alkenes has been
developed using pinacolborane (HBpin) as a reducing reagent and 1-ethyl …