Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view

J Escorihuela, A Lledós, G Ujaque - Chemical Reviews, 2023 - ACS Publications
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Challenges in catalytic hydrophosphination

CA Bange, R Waterman - Chemistry–A European Journal, 2016 - Wiley Online Library
Despite significant advances, metal‐catalyzed hydrophosphination has ample room for
discovery, growth, and development. Many of the key successes in metal‐catalyzed …

Rare-earth-catalyzed selective 1, 4-hydrosilylation of branched 1, 3-enynes giving tetrasubstituted silylallenes

W Chen, C Jiang, J Zhang, J Xu, L Xu… - Journal of the …, 2021 - ACS Publications
Allenes are versatile synthons in organic synthesis and medicinal chemistry because of their
diverse reactivities. Catalytic 1, 4-hydrosilylation of 1, 3-enynes may present the …

Recent advances in organo-lanthanides and actinides mediated hydroaminations

H Liu, S Saha, MS Eisen - Coordination Chemistry Reviews, 2023 - Elsevier
Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

Metal‐Catalyzed Hydrophosphination

BT Novas, R Waterman - ChemCatChem, 2022 - Wiley Online Library
Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …

Broken promises? On the continued challenges faced in catalytic hydrophosphination

S Lau, TM Hood, RL Webster - ACS catalysis, 2022 - ACS Publications
In this Perspective, we discuss what we perceive to be the continued challenges faced in
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …

Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds

AA Trifonov, IV Basalov, AA Kissel - Dalton Transactions, 2016 - pubs.rsc.org
Use of organolanthanides in the catalytic intermolecular hydrophosphination and
hydroamination of multiple C–C bonds - Dalton Transactions (RSC Publishing) DOI:10.1039/C6DT03913H …

Catalyst-and solvent-free hydrophosphination and multicomponent hydrothiophosphination of alkenes and alkynes

Y Moglie, MJ González-Soria, I Martín-García… - Green …, 2016 - pubs.rsc.org
The hydrophosphination of carbon–carbon multiple bonds has been generally performed
under acid, base or metal catalysis in different solvents. Herein, alkyl and alkenyl tertiary …

Lanthanum Ate Amide-Catalyzed Regio-and Stereoselective Hydrosilylation of Internal Alkynes

X Xu, A Gao, W Chen, X Xu, J Li, C Cui - ACS Catalysis, 2023 - ACS Publications
Silylalkenes are important synthetic intermediates to substituted alkenes and silicon
materials and can be directly obtained by the catalytic selective hydrosilylation of alkynes. In …