Quo Vadis carbanionic polymerization?

K Ntetsikas, V Ladelta, S Bhaumik… - ACS Polymers …, 2022 - ACS Publications
Living anionic polymerization will soon celebrate 70 years of existence. This living
polymerization is considered the mother of all living and controlled/living polymerizations …

Progress in the preparation of phosphorus-containing polymers via phosphorus trichloride-free routes

YL Hong, Y Liu, C Wang, XQ Fang, F Yang… - European Polymer …, 2023 - Elsevier
Abstract Phosphorus (P)-containing polymers (PCPs) are functional materials that have
attracted extensive attention from both academia and industry. PCPs are widely used in …

Thorium (IV) and Uranium (IV) Phosphaazaallenes

P Rungthanaphatsophon, OJ Fajen, SP Kelley… - Inorganics, 2019 - mdpi.com
The synthesis of tetravalent thorium and uranium complexes with the phosphaazaallene
moiety,[N (tBu) C= P (C6H5)] 2−, is described. The reaction of the bis (phosphido) …

Coordination-induced polymerization of P═C bonds leads to regular (P─C)n polycarbophosphanes

Y Mei, JJ Gamboa-Carballo, Y Bao, N Wu… - Science …, 2021 - science.org
The replacement of carbon in (C─ C) n chains of polyolefins by phosphorus leads to
polycarbophosphanes (P─ C) n, which may possess unique chemical and physical …

Di-and tri-block copolymers from the sequential living anionic copolymerization a phosphaalkene with styrene

T Zhang, ED Conrad, DP Gates - Polymer, 2022 - Elsevier
The living anionic polymerization of the phosphaalkene, MesP= CPh 2 (PA), affords a series
of poly (methylenephosphine)(PMP) homo-and block co-polymers with styrene (S) …

Addition–Isomerization Anionic Homopolymerization of a 1, 1-Diphenylethylene Derivative

D Tanioka, K Adachi - Macromolecules, 2022 - ACS Publications
The chain-growth polymerization of a 1, 1-diphenylethylene (DPE) derivative was achieved
by employing addition–isomerization anionic polymerization. A homopolymer was obtained …

Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

JAL Wells, MA Shameem, AK Gupta… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The heterofulvenoid cyclopentadithiophene-phosphaalkene is a versatile building block for
opto-electronic tuning with donor and acceptor moieties. Both the annulated thienyl rings …

Isolable Phosphaalkenes Bearing 2, 4, 6-Trimethoxyphenyl and 2, 6-Bis (trifluoromethyl) phenyl as P-Substituents

Z Han, D Rohner, K Samedov… - The Journal of Organic …, 2020 - ACS Publications
The multistep synthesis and characterization of new P═ C analogues of olefins from readily
available starting materials is reported. Specifically, the phosphaalkenes TMOP–P═ CPh2 …

Diastereoselective synthesis of spirodihydrobenzofuran analogues of the natural product filifolinol

M Becerra‐Ruiz, A Galdámez, B Modak… - …, 2020 - Wiley Online Library
Filifolinol is a natural occurring spirodihydrobenzofuran isolated from the resinous exudates
of Heliotropium filifolium, a Chilean endemic shrub. Filifolinol and some of its derivatives …

Chemical-and light-induced isomerization of the P= C bond of a 1-phosphabutadiene

HTG Walsgrove, P Dabringhaus… - Canadian Journal of …, 2020 - cdnsciencepub.com
Treatment of Mes* P= C (Si (CH3) 3) Br with CH2= CHMgBr in the presence of Pd (0) affords
1-phosphabutadiene Mes* P= C (Si (CH3) 3)–CH= CH2 (1) selectively as the Z isomer …