The discovery of titanium alkoxide-catalyzed cyclopropanation of carboxylic esters with
Grignard reagents in the late 1980s (Kulinkovich reaction) commenced the era of …

Herein, we disclose the first and simple one‐pot‐two‐step process to the synthesis of 1‐
difluoromethyl 1, 4‐diketones, through Mn‐catalyzed radical Brook rearrangement. The …

Titanium enolates, in situ-generated from readily available ketones and titanium
tetraisopropoxide, undergo domino cross-coupling/cyclodehydration or domino Aldol …

Summary This Chapter Contains Sections titled: Oxidation by Metal Ions and Related
Species Chromium, Manganese, Nickel, and Cobalt Copper, Silver, Gold, and Thallium …

Enantioselective gold (I) catalysis is notoriously challenging. The preferred linear
coordination of the metal places the ancillary chiral ligand and the substrate opposite to …