Platinum-catalyzed hydrosilylation in polymer chemistry

RY Lukin, AM Kuchkaev, AV Sukhov… - Polymers, 2020 - mdpi.com
This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of
application of these catalysts is the curing of silicone polymers. Since the 1960s, this area …

Broad spectrum antimicrobial PDMS-based biomaterial for catheter fabrication

A Armugam, SP Teong, DSW Lim, SP Chan… - Biomaterials …, 2021 - spj.science.org
Background In addition to the widespread use of antibiotics in healthcare settings, the
current COVID-19 pandemic has escalated the emergence of antibiotic resistance …

White-Light initiated Mn2 (CO) 10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes

IK Goncharova, SA Filatov, AP Drozdov… - Journal of …, 2024 - Elsevier
This study presents a highly efficient and mild method for radical hydrosilylation of alkenes.
The reaction proceeds under white-light, in the presence of Mn 2 (CO) 10 pre-catalyst and …

Cyclic metal (oid) clusters control platinum-catalysed hydrosilylation reactions: from soluble to zeolite and MOF catalysts

M Rivero-Crespo, J Oliver-Meseguer, K Kapłońska… - Chemical …, 2020 - pubs.rsc.org
The Pt-catalysed addition of silanes to functional groups such as alkenes, alkynes,
carbonyls and alcohols, ie the hydrosilylation reaction, is a fundamental transformation in …

Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts

S Shimada - Perspectives of Hydrosilylation Reactions, 2023 - Springer
This chapter summarizes recent advances of group 10 transition metal hydrosilylation
catalysts from 2015 onward. Since the discovery of Speier's catalyst in 1957, homogeneous …

Boosted urea electrooxidation activity by dynamic steady blending CoOOH–Ni (OH) 2 nanoclusters for H 2 production in a pH-asymmetric electrolyzer

SM Peng, ST Chang, CC Chang… - Journal of Materials …, 2024 - pubs.rsc.org
Electrochemical urea oxidation reaction (UOR) is a promising alternative to the oxygen
evolution reaction for reducing the overall potential of the hydrogen evolution reaction …

Visible-light-induced synthesis of “surfactant-free” Pt nanoparticles in ethylene glycol as a synthetic approach for mechanistic studies on nanoparticle formation

J Schröder, S Neumann, S Kunz - The Journal of Physical …, 2020 - ACS Publications
The alkaline polyol synthesis of “surfactant-free” Pt nanoparticles (NPs) is a straightforward
approach to synthesize NPs as colloids. Even challenges such as size control have been …

Prospects in Sustainable Hydrosilylation by Biphase Catalysis

IK Goncharova, IP Beletskaya… - ChemCatChem, 2024 - Wiley Online Library
This concept addresses the main economic, environmental, scientific and technological
issues associated with the use of homogeneous Pt‐catalysts in the important industrial …

Discrete Au1(0) Stabilized by 15-Crown-5 for High-Efficiency Catalytic Reduction of Nitrophenol and Nitroaniline

X Shen, K Liu - Catalysts, 2023 - mdpi.com
Single-atom catalysts (SACs) have been synthesized using a variety of methods in recent
years, and they have shown excellent catalytic activities. However, metal atoms show a high …

Transportable Mononuclear Metal Atoms as Building Blocks for Bottom‐up Material Fabrication: Pt1(0) and Au1(0) Atoms in Stock Solutions

H Li, C Liang, P Gao, G Hou, K Liu, W Liu… - …, 2020 - Wiley Online Library
Premade and readily transportable mononuclear zero‐valent metal atoms in stock solvents
offer the potential capability for bottom‐up designable metallic material fabrication. This work …