Structural and functional analogues of the active sites of the [Fe]-,[NiFe]-, and [FeFe]-hydrogenases
C Tard, CJ Pickett - Chemical reviews, 2009 - ACS Publications
This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …
functional analogues of the three classes of hydrogenases. This chemistry has grown …
Phospha-Mannich reactions of RPH2, R2PH, and R3P
DV Moiseev, BR James - Phosphorus, Sulfur, and Silicon and the …, 2022 - Taylor & Francis
Phosphorus-based Mannich-type reactions (phospha-Mannich reactions) of primary or
secondary phosphines with carbonyl compounds and amines (R2NH, RNH2, and NH3) …
secondary phosphines with carbonyl compounds and amines (R2NH, RNH2, and NH3) …
Electrode initiated proton-coupled electron transfer to promote degradation of a nickel (II) coordination complex
BD McCarthy, CL Donley, JL Dempsey - Chemical Science, 2015 - pubs.rsc.org
A Ni (II) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that
can evolve hydrogen under reducing and protic conditions. An electrochemical study …
can evolve hydrogen under reducing and protic conditions. An electrochemical study …
Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species
DJ Martin, BD McCarthy, CL Donley… - Chemical …, 2015 - pubs.rsc.org
Electrochemical hydrogenation of a homogeneous nickel complex to form a surface
adsorbed hydrogen-evolving species - Chemical Communications (RSC Publishing) DOI:10.1039/C4CC08662G …
adsorbed hydrogen-evolving species - Chemical Communications (RSC Publishing) DOI:10.1039/C4CC08662G …
Mixed-valence nickel–iron dithiolate models of the [NiFe]-hydrogenase active site
D Schilter, MJ Nilges, M Chakrabarti… - Inorganic …, 2012 - ACS Publications
A series of mixed-valence nickel–iron dithiolates is described. Oxidation of (diphosphine) Ni
(dithiolate) Fe (CO) 3 complexes 1, 2, and 3 with ferrocenium salts affords the corresponding …
(dithiolate) Fe (CO) 3 complexes 1, 2, and 3 with ferrocenium salts affords the corresponding …
The Role of the Second Coordination Sphere of [Ni(PCy2NBz2)2](BF4)2 in Reversible Carbon Monoxide Binding
AD Wilson, K Fraze, B Twamley, SM Miller… - Journal of the …, 2008 - ACS Publications
The complex [Ni (PCy2NBz2) 2](BF4) 2, 1, reacts rapidly and reversibly with carbon
monoxide (1 atm) at 25° C to form [Ni (CO)(PCy2NBz2) 2](BF4) 2, 2, which has been …
monoxide (1 atm) at 25° C to form [Ni (CO)(PCy2NBz2) 2](BF4) 2, 2, which has been …
Mononuclear nickel (II) dithiolate complexes with chelating diphosphines: Insight into protonation and electrochemical proton reduction
XL Gu, JR Li, QL Li, Y Guo, XB Jing, ZB Chen… - Journal of Inorganic …, 2021 - Elsevier
Inspired by the metal active sites of [FeFe]-and [NiFe]‑hydrogenases, a series of
mononuclear Ni (II) ethanedithiolate complexes [{(Ph 2 PCH 2) 2×} Ni (SCH 2 CH 2 S)](X …
mononuclear Ni (II) ethanedithiolate complexes [{(Ph 2 PCH 2) 2×} Ni (SCH 2 CH 2 S)](X …
Imidazole-Containing (N3S)-NiII Complexes Relating to Nickel Containing Biomolecules
RM Jenkins, ML Singleton, E Almaraz… - Inorganic …, 2009 - ACS Publications
Dimeric (N2S) Ni complexes and the monomeric N2S2 bismercaptodiazacycloheptane
nickel complex,(bme-dach) Ni, serve as precursors to two N2-, N′-/S-complexes where …
nickel complex,(bme-dach) Ni, serve as precursors to two N2-, N′-/S-complexes where …
A Heterobimetallic W–Ni Complex Containing a Redox-Active W[SNS]2 Metalloligand
KE Rosenkoetter, JW Ziller, AF Heyduk - Inorganic Chemistry, 2016 - ACS Publications
The tungsten complex W [SNS] 2 ([SNS] H3= bis (2-mercapto-4-methylphenyl) amine) was
bound to a Ni (dppe)[dppe= 1, 2-bis (diphenylphosphino) ethane] fragment to form the new …
bound to a Ni (dppe)[dppe= 1, 2-bis (diphenylphosphino) ethane] fragment to form the new …
Shift of the reduction potential of nickel (ii) Schiff base complexes in the presence of redox innocent metal ions
With the objective of gaining insight into the modulation of the reduction potential of the Ni
(II/I) couple, we have synthesized two mononuclear nickel (II) complexes, NiLen (H2Len= N …
(II/I) couple, we have synthesized two mononuclear nickel (II) complexes, NiLen (H2Len= N …