Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration

L Capaldo, D Ravelli, M Fagnoni - Chemical Reviews, 2021 - ACS Publications
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Cyclohexane oxidation continues to be a challenge

U Schuchardt, D Cardoso, R Sercheli, R Pereira… - Applied Catalysis A …, 2001 - Elsevier
Many efforts have been made to develop new catalysts to oxidize cyclohexane under mild
conditions. Herein, we review the most interesting systems for this process with different …

Selective C(sp3)−H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow

G Laudadio, S Govaerts, Y Wang, D Ravelli… - Angewandte …, 2018 - Wiley Online Library
A mild and selective C (sp3)− H aerobic oxidation enabled by decatungstate photocatalysis
has been developed. The reaction can be significantly improved in a microflow reactor …

Photocatalysis with Organized Systems for the Oxofunctionalization of Hydrocarbons by O2

A Maldotti, A Molinari, R Amadelli - Chemical Reviews, 2002 - ACS Publications
A great deal of attention has been devoted in the last years to photocatalytic processes both
in the homogeneous phase and in heterogeneous systems. In its broadest sense …

Electrochemistry and photoredox catalysis: A comparative evaluation in organic synthesis

RH Verschueren, WM De Borggraeve - Molecules, 2019 - mdpi.com
This review provides an overview of synthetic transformations that have been performed by
both electro-and photoredox catalysis. Both toolboxes are evaluated and compared in their …

Synthesis and photocatalytic oxidation properties of iron doped titanium dioxide nanosemiconductor particles

X Li, PL Yue, C Kutal - New journal of chemistry, 2003 - pubs.rsc.org
The structure, physical characteristics and selective photocatalytic oxidation properties of
quantum confined nanosize iron doped TiO2 (Q-TiO2/Fe3+) particles were studied by TG …

Synthesis, electrochemical and photophysical properties of covalently linked porphyrin–polyoxometalates

C Allain, D Schaming, N Karakostas, M Erard… - Dalton …, 2013 - pubs.rsc.org
Two covalently linked porphyrin–polyoxometalate hybrids have been prepared: an
Anderson-type hexamolybdate [N (C4H9) 4] 3 [MnMo6O18 {(OCH2) 3CNHCO (ZnTPP)} 2] …

Recent progress in strategies to enhance the photocatalytic oxidation performance of cyclohexane

H Huo, B Guo, G Ma, Y Xiang, H Lv, S Li, Z Liu… - Journal of …, 2024 - Elsevier
The photo-oxidation of cyclohexane to produce cyclohexanol and cyclohexanone (a mixture
known as KA oil) is one of the important reactions in CH activation. Cyclohexanol and …

Photocatalytic oxygenation of cyclohexane on titanium dioxide suspensions: Effect of the solvent and of oxygen

P Boarini, V Carassiti, A Maldotti, R Amadelli - Langmuir, 1998 - ACS Publications
The photoassisted monooxygenation of C6H12 to C6H10O and C6H11OH by molecular
oxygen has been studied on TiO2 powder catalyst dispersed in neat C6H12 and in …

Reactivity studies of biomimetic catalytic epoxidation of alkenes with tetrabutylammonium periodate in the presence of various manganese porphyrins and nitrogen …

D Mohajer, G Karimipour, M Bagherzadeh - New Journal of Chemistry, 2004 - pubs.rsc.org
Highly selective epoxidation (> 95%) of unfunctionalized alkenes was performed by
tetrabutylammonium periodate in the presence of six different phenyl substituted …