Recent Advances in the Synthesis of Indolines via Dearomative Annulation of N‐acylindoles
CC Lu, BY Hao, YP Han… - Asian Journal of Organic …, 2022 - Wiley Online Library
Polycyclic fused indoline derivatives, specifically those bearing tertiary or quaternary carbon
stereocenters at C2 and C3 positions, stand as an important class of nitrogen‐containing …
stereocenters at C2 and C3 positions, stand as an important class of nitrogen‐containing …
Copper (ii)-catalyzed oxidative ipso-annulation of N-arylpropiolamides and biaryl ynones with 1, 3-diketones: construction of diketoalkyl spiro-trienones
CR Reddy, DH Kolgave, U Ajaykumar… - Organic & Biomolecular …, 2022 - pubs.rsc.org
An unprecedented copper-catalyzed ipso-annulation reaction of N-(p-methoxyaryl)
propiolamides with 1, 3-diketones has been developed, which enables the assembly of …
propiolamides with 1, 3-diketones has been developed, which enables the assembly of …
CAN-Promoted Thiolative ipso-Annulation of Unactivated N-Benzyl Acrylamides: Access to SCN/SCF3/SO2Ar Containing Azaspirocycles
CR Reddy, U Ajaykumar, DH Kolgave… - The Journal of Organic …, 2023 - ACS Publications
A variety of acrylamides holding an unactivated N-benzyl group underwent dearomative
ipso-cyclization induced by sulfur-centered radicals (SCN/SCF3/SO2Ar) in the presence of …
ipso-cyclization induced by sulfur-centered radicals (SCN/SCF3/SO2Ar) in the presence of …
Selective Synthesis of Mono-and Bis-Phosphorylated (Dihydro) pyrans via TMSCl-Mediated Cascade Phosphorylation Cycloisomerization of Enynones
YF Qiu, Q Wang, JH Cao, DQ Xue, M Li, ZJ Quan… - Organic …, 2024 - ACS Publications
A chlorotrimethylsilane (TMSCl)-mediated cascade phosphorylation and cycloisomerization
of enynones with diphenylphosphine oxides is presented. This methodology enables the …
of enynones with diphenylphosphine oxides is presented. This methodology enables the …
Visible light-enabled synthesis of phosphorylated indolizine and pyridoindole derivatives via HAT-mediated radical cascade cyclization
K Shen, C Feng, Y Liu, D Yi, P Lin, H Li… - Organic & …, 2023 - pubs.rsc.org
A visible light-enabled cascade cyclization strategy is disclosed with concomitant
phosphorylation and heterocycle construction. It provides a novel and environmentally …
phosphorylation and heterocycle construction. It provides a novel and environmentally …
Organocatalyzed Photoelectrochemistry for the Generation of Acyl and Phosphoryl Radicals through Hydrogen Atom-Transfer Process
H He, CM Pan, ZW Hou, M Sun… - The Journal of Organic …, 2024 - ACS Publications
An organocatalyzed photoelectrochemical method for the generation of acyl and phosphoryl
radicals from formamides, aldehydes, and phosphine oxides has been developed. This …
radicals from formamides, aldehydes, and phosphine oxides has been developed. This …
Photo-induced phosphorylation/cyclization of N-homoallyl and N-allyl aldehyde hydrazones to access phosphorylated tetrahydropyridazines and dihydropyrazoles
L Liu, Y Wu, C Xiang, JT Yu, C Pan - Chemical Communications, 2024 - pubs.rsc.org
A photocatalytic radical carbophosphorylation/cyclization of N-homoallyl aldehyde
hydrazones with phosphine oxides was developed under metal-free conditions, achieving …
hydrazones with phosphine oxides was developed under metal-free conditions, achieving …
[HTML][HTML] Photoinduced radical cascade brominative addition/spirocyclization of N-arylpropiolamides and CBr4 with O2 as oxidant
ZW Wu, HH Kong, Y Wei, WC Zhou, L Wang… - Green Synthesis and …, 2024 - Elsevier
A visible-light-induced brominated spirocyclization of N-arylpropiolamides and CBr 4 for the
synthesis of 3-bromo-azaspiro [4, 5] trienones is reported here. This process allows the …
synthesis of 3-bromo-azaspiro [4, 5] trienones is reported here. This process allows the …
Electrochemical Synthesis of Phosphorylated Indoles and Trp-Containing Oligopeptides
J Wang, Z Zhang, Y Shen, Y Zhao, J Wu - Organic Letters, 2024 - ACS Publications
Cp2Fe-mediated electrochemical synthesis of phosphorylated indoles and Trp-containing
oligopeptides has been developed, which eliminates the need for external oxidants and …
oligopeptides has been developed, which eliminates the need for external oxidants and …
Light‐Promoted Germylation of Aryl Propiolamides/Alkynoates: Synthesis of Ge‐Containing Spiro [4.5] trienones and Vinylgermanes
Y Luo, L Lv, Z Li - ChemCatChem, 2023 - Wiley Online Library
The light‐promoted regioselective germylation of aryl propiolamides/alkynoates with
germanium hydrides is reported. The germyl‐containing spiro [4.5] trienones were obtained …
germanium hydrides is reported. The germyl‐containing spiro [4.5] trienones were obtained …