The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

The catalytic asymmetric addition reactions of organometallic reagents to CdN double bonds
of imines are fundamentally important processes, which provide convenient and versatile …

Asymmetric reductive amination (ARA) of a prochiral carbonyl compound with an amine
using a H2/hydrogen surrogate is a concise and operationally simple method for the …

A visible-light-initiated α-perfluoroalkyl-β-heteroarylation of various alkenes with
perfluoroalkyl iodides and quinoxalin-2 (1 H)-ones is presented. This three-component …

Conspectus The chemistry of hydrazones has gained great momentum due to their
involvement throughout the evolution of organic synthesis. Herein, we discuss the …

An efficient catalytic system for the alkylation of amines with either alcohols or amines under
mild conditions has been developed, using cyclometallated iridium complexes as catalysts …

Asymmetric reductive amination (ARA) affords synthetically valuable chiral amines
straightforwardly. This chapter reviews the recent advances made in the area, focusing on …

An efficient and general method for C (sp2)–H difluoroalkylation of aldehyde derived
hydrazones via a CuII/B2pin2-catalyzed reaction between difluoroalkyl bromides and …

The Cu-catalyzed direct difluoroalkylation of aldehyde hydrazones with functionalized
difluoromethyl bromides is described. The reaction yields stereodefined α, α–difluoro-β-keto …

Successful implementation of a catalytic asymmetric synthesis strategy to produce
enantiomerically enriched compounds requires the adoption of suitable prochiral substrates …