The golden age of transfer hydrogenation
D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
Hydroxide complexes of the late transition metals: Organometallic chemistry and catalysis
Transition metal hydroxides of the late transition metals are now relatively common, and play
a special role in both the synthesis of new complexes and in important catalytic reactions …
a special role in both the synthesis of new complexes and in important catalytic reactions …
On the concept of hemilability: Insights into a donor-functionalized iridium (I) NHC motif and its impact on reactivity
Novel iridium (I) complexes bearing N-donor-functionalized N-heterocyclic carbene ligands
were synthesized. Although hemilabile coordination of the attached donor is considered …
were synthesized. Although hemilabile coordination of the attached donor is considered …
Hydroxo–rhodium–N-heterocyclic carbene complexes as efficient catalyst precursors for alkyne hydrothiolation
The new Rh–hydroxo dinuclear complexes stabilized by an N-heterocyclic carbene (NHC)
ligand of type [Rh (μ-OH)(NHC)(η2-olefin)] 2 (coe, IPr (3), IMes (4); ethylene, IPr (5)) are …
ligand of type [Rh (μ-OH)(NHC)(η2-olefin)] 2 (coe, IPr (3), IMes (4); ethylene, IPr (5)) are …
Iridium (I) hydroxides: powerful synthons for bond activation
BJ Truscott, DJ Nelson, C Lujan… - … A European Journal, 2013 - Wiley Online Library
A family of iridium (I) hydroxides of the form [Ir (cod)(NHC)(OH)](cod= 1, 5‐cyclooctadiene,
NHC= N‐heterocyclic carbene) is reported. Single‐crystal X‐ray analyses and …
NHC= N‐heterocyclic carbene) is reported. Single‐crystal X‐ray analyses and …
Porous aromatic frameworks (PAFs) as efficient supports for N-heterocyclic carbene catalysts
E Rangel-Rangel, E Verde-Sesto… - Catalysis Science & …, 2016 - pubs.rsc.org
Porous polymeric aromatic frameworks (PAFs) have high porosity and surface area, as well
as high physicochemical stability; such characteristics are important in the design of …
as high physicochemical stability; such characteristics are important in the design of …
Oxidation of Half-Lantern Pt2(II,II) Compounds by Halocarbons. Evidence of Dioxygen Insertion into a Pt(III)–CH3 Bond
V Sicilia, M Baya, P Borja, A Martín - Inorganic Chemistry, 2015 - ACS Publications
The half-lantern compound [{Pt (bzq)(μ-N^ S)} 2](1)[bzq= benzo [h] quinoline, HN^ S= 2-
mercaptopyrimidine (C4H3N2HS)] reacts with CH3I and haloforms CHX3 (X= Cl, Br, I) to …
mercaptopyrimidine (C4H3N2HS)] reacts with CH3I and haloforms CHX3 (X= Cl, Br, I) to …
General Route to Cyclobutadiene Rhodium Complexes
DS Perekalin, NV Shvydkiy… - … A European Journal, 2015 - Wiley Online Library
Cyclobutadiene rhodium complexes bear high potential for applications in organometallic
synthesis and catalysis. We have found that the cyclobutadiene complexes with …
synthesis and catalysis. We have found that the cyclobutadiene complexes with …
Synthesis and characterization of an iridium triphyrin complex
A sandwich complex of iridium (III) benzotriphyrin (2) has been synthesized from free-base
benzotriphyrin (1) and [IrCl (cod)] 2 (COD= 1, 5-cyclooctadiene). The COD ring was …
benzotriphyrin (1) and [IrCl (cod)] 2 (COD= 1, 5-cyclooctadiene). The COD ring was …
The application of dichloromethane and chloroform as reagents in organic synthesis
A Tlili, J Schranck - Solvents as Reagents in Organic Synthesis …, 2017 - books.google.com
Chlorine derivatives of methane belong to the most important commodity chemicals among
the halogenated hydrocarbons [1]. In particular, dichloromethane and chloroform …
the halogenated hydrocarbons [1]. In particular, dichloromethane and chloroform …