Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …
side chains that are densely grafted from a backbone that is typically linear. Their unique …
Direct observation of ring polymer dynamics in the flow-gradient plane of shear flow
MQ Tu, M Lee, RM Robertson-Anderson… - …, 2020 - ACS Publications
Ring polymers are a unique class of macromolecules that lack free ends and show
qualitatively different dynamics compared to linear chains. Despite recent progress, the …
qualitatively different dynamics compared to linear chains. Despite recent progress, the …
[HTML][HTML] Dynamics and rheology of ring-linear blend semidilute solutions in extensional flow: Single molecule experiments
Ring polymers exhibit unique flow properties due to their closed chain topology. Despite
recent progress, we have not yet achieved a full understanding of the nonequilibrium flow …
recent progress, we have not yet achieved a full understanding of the nonequilibrium flow …
Hydrodynamic inflation of ring polymers under shear
M Liebetreu, CN Likos - Communications Materials, 2020 - nature.com
Hydrodynamic interactions can dramatically influence the dynamics of fully flexible, ring-
shaped polymers in ways unknown for any other polymer architecture or topology. Tumbling …
shaped polymers in ways unknown for any other polymer architecture or topology. Tumbling …
Effects of linking topology on the shear response of connected ring polymers: Catenanes and bonded rings flow differently
We perform computer simulations of mechanically linked (poly [2] catenanes, PC) and
chemically bonded (bonded rings, BR) pairs of self-avoiding ring polymers in steady shear …
chemically bonded (bonded rings, BR) pairs of self-avoiding ring polymers in steady shear …
Nonmonotonic dependence of comb polymer relaxation on branch density in semidilute solutions of linear polymers
The dynamics of branched polymers in semidilute solutions are thought to depend on a
coupling between polymer chain architecture, intermolecular excluded volume interactions …
coupling between polymer chain architecture, intermolecular excluded volume interactions …
[HTML][HTML] Dynamics and rheology of ring-linear blend semidilute solutions in extensional flow. Part I: Modeling and molecular simulations
We use Brownian dynamics (BD) simulations and single molecule experiments to
investigate the influence of topological constraints and hydrodynamic interactions on the …
investigate the influence of topological constraints and hydrodynamic interactions on the …
Intrinsic surface characteristics and dynamic mechanisms of ring polymers in solution and melt under shear flow
SH Jeong, S Cho, EJ Roh, TY Ha, JM Kim… - Macromolecules, 2020 - ACS Publications
Based on the novel viewpoint that ring polymers, with their closed-loop molecular geometry,
are naturally defined by an intrinsic two-dimensional topological surface, we analyzed the …
are naturally defined by an intrinsic two-dimensional topological surface, we analyzed the …
Melt rheology of short-chain branched ring polymers in shear flow
SH Jeong, TY Ha, S Cho, EJ Roh, JM Kim… - Macromolecules, 2021 - ACS Publications
We examined the general rheological characteristics of short-chain branched (SCB) ring
polyethylene (PE) melts using atomistic nonequilibrium molecular dynamics (NEMD) …
polyethylene (PE) melts using atomistic nonequilibrium molecular dynamics (NEMD) …
Interfacial Polymer Rheology of Entangled Short-Chain Branched Ring Melts in Shear Flow
TY Ha, SH Jeong, C Baig - Macromolecules, 2024 - ACS Publications
We present a detailed analysis of the rheological behavior of entangled short-chain-
branched (SCB) ring polymers at interfaces via direct comparison with the corresponding …
branched (SCB) ring polymers at interfaces via direct comparison with the corresponding …