The concerted action of a Lewis acid and base can activate H 2 and other small molecules.
Such frustrated Lewis pairs (FLPs) have garnered much attention and prompted many …

In contrast to transition metal-catalysed C–H functionalisation, highly efficient construction of
C–C and C–X (X= N, O, S, B, Si, etc.) bonds through metal-free catalytic C–H …

The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …

Hydrogenated nitrogen heterocyclic compounds play a critical role in the pharmaceutical,
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …

Herein, the first acceptorless dehydrogenation of tetrahydroquinolines (THQs), indolines,
and other related N‐heterocycles, by merging visible‐light photoredox catalysis and cobalt …

Hybrid catalyst systems to achieve acceptorless dehydrogenation of N-heterocycles and
tetrahydronaphthalenes model substrates for liquid organic hydrogen carriers were …

TiO2 is an effective and extensively employed photocatalyst, but its practical use in visible-
light-mediated organic synthesis is mainly hindered by its wide band gap energy. Herein, we …

The manipulation of amino C–H bonds has garnered significant interest from the synthetic
community due to its inherently high atom, step and redox economy. This Tutorial Review …

An efficient deuteration process of β-amino C–H bonds in various N-alkylamine-based
pharmaceutical compounds has been developed. Catalytic reactions begin with the action of …

Conspectus The activation of molecular hydrogen by main-group element catalysts is an
extremely important approach to metal-free hydrogenations. These so-called frustrated …