Pancake bonds: π-Stacked dimers of organic and light-atom radicals
KE Preuss - Polyhedron, 2014 - Elsevier
The nature of the chemical bond is fundamental to the modern concept of chemistry. Species
that exhibit unusual interactions provide a valuable challenge to current theoretical models …
that exhibit unusual interactions provide a valuable challenge to current theoretical models …
Chalcogen bonding in synthesis, catalysis and design of materials
Chalcogen bonding is a type of noncovalent interaction in which a covalently bonded
chalcogen atom (O, S, Se or Te) acts as an electrophilic species towards a nucleophilic …
chalcogen atom (O, S, Se or Te) acts as an electrophilic species towards a nucleophilic …
Breathing some new life into an old topic: Chalcogen-nitrogen π-heterocycles as electron acceptors
AV Lonchakov, OA Rakitin, NP Gritsan, AV Zibarev - Molecules, 2013 - mdpi.com
Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-
heterocycles, mostly 1, 2, 5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused …
heterocycles, mostly 1, 2, 5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused …
Multifunctional dithiadiazolyl radicals: fluorescence, electroluminescence, and photoconducting behavior in pyren-1′-yl-dithiadiazolyl
The pyren-1′-yl-functionalized dithiadiazolyl (DTDA) radical, C16H9CNSSN (1), is
monomeric in solution and exhibits fluorescence in the deep-blue region of the visible …
monomeric in solution and exhibits fluorescence in the deep-blue region of the visible …
Fine-Tuning the Single-Molecule Magnet Properties of a [Dy(III)-Radical]2 Pair
EM Fatila, M Rouzières, MC Jennings… - Journal of the …, 2013 - ACS Publications
A supramolecular species composed of a pair of nonequivalent Dy (III)–radical complexes
exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic …
exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic …
Nanocrystals of a metal–organic complex exhibit remarkably high conductivity that increases in a single-crystal-to-single-crystal transformation
KM Hutchins, TP Rupasinghe, LR Ditzler… - Journal of the …, 2014 - ACS Publications
Ag (I) is used to form a π-stacked metal–organic solid that exhibits remarkably high electrical
conductivity. The solid undergoes a single-crystal-to-single-crystal [2+ 2] photodimerization …
conductivity. The solid undergoes a single-crystal-to-single-crystal [2+ 2] photodimerization …
Magnetic Transition in Organic Radicals: The Crystal Engineering Aspects
Spin–Spin interactions between unpaired electrons in organic radicals are of utter
importance from the viewpoint of molecular magnetism and the development of smart …
importance from the viewpoint of molecular magnetism and the development of smart …
Magnetic ordering and anisotropy in heavy atom radicals
Recent developments in stable radical chemistry have afforded “heavy atom” radicals,
neutral open-shell (S= 1/2) molecular species containing heavy p-block elements (S, Se) …
neutral open-shell (S= 1/2) molecular species containing heavy p-block elements (S, Se) …
Heat, pressure and light-induced interconversion of bisdithiazolyl radicals and dimers
The heterocyclic bisdithiazolyl radical 1b (R1= Me, R2= F) crystallizes in two phases. The α-
phase, space group P 21/n, contains two radicals in the asymmetric unit, both of which adopt …
phase, space group P 21/n, contains two radicals in the asymmetric unit, both of which adopt …
Mechanically compliant single crystals of a stable organic radical
Mechanically compliant organic crystals are the foundation of the development of future
flexible, light-weight single-crystal electronics, and this requires reversibly deformable …
flexible, light-weight single-crystal electronics, and this requires reversibly deformable …