Presenting porous–organic–polymers as next-generation invigorating materials for nanoreactors

C Sarkar, SC Shit, N Das, J Mondal - Chemical Communications, 2021 - pubs.rsc.org
Porous organic polymers (POPs) represent an emerging class of porous organic materials
which mainly comprise organic building blocks that are interconnected via strong covalent …

Porous organic polymers containing active metal centers as catalysts for synthetic organic chemistry

S Kramer, NR Bennedsen, S Kegnæs - ACS Catalysis, 2018 - ACS Publications
Porous organic polymers (POPs) containing catalytically active mononuclear metal centers
can bridge the gap between homogeneous and heterogeneous catalysis. These materials …

H2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H2 Activation at the Metal–Support Interface

T Whittaker, KBS Kumar, C Peterson… - Journal of the …, 2018 - ACS Publications
Water adsorbed at the metal–support interface (MSI) plays an important role in multiple
reactions. Due to its importance in CO preferential oxidation (PrOx), we examined H2 …

Metal‐Decorated Porous Organic Polymers: Bridged the Gap between Organic and Inorganic Scaffolds

Z Gao, Y Liu, S Wu, J Tang, K Yuan… - Chinese Journal of …, 2024 - Wiley Online Library
Comprehensive Summary Advanced functionalization‐decorated porous organic polymers
(POPs) are emerging as a prominent research focus, spanning from their construction to …

New tricks for an old dog: Aluminum compounds as catalysts in reduction chemistry

GI Nikonov - ACS Catalysis, 2017 - ACS Publications
This Perspective discusses recent results on the application of aluminum compounds in
catalytic reduction processes, such as hydrogenation, transfer hydrogenation …

LiAlH4: From Stoichiometric Reduction to Imine Hydrogenation Catalysis

H Elsen, C Färber, G Ballmann… - Angewandte Chemie …, 2018 - Wiley Online Library
Imine‐to‐amine conversion with catalytic instead of stoichiometric quantities of LiAlH4 is
demonstrated (85° C, catalyst loading≥ 2.5 mol%, pressure≥ 1 bar). The effects of …

Chemoselective hydrogenation with supported organoplatinum (IV) catalyst on Zn (II)-modified silica

J Camacho-Bunquin, M Ferrandon… - Journal of the …, 2018 - ACS Publications
Well-defined organoplatinum (IV) sites were grafted on a Zn (II)-modified SiO2 support via
surface organometallic chemistry in toluene at room temperature. Solid-state spectroscopies …

Organoaluminum compounds as catalysts for monohydroboration of carbodiimides

Q Shen, X Ma, W Li, W Liu, Y Ding… - … A European Journal, 2019 - Wiley Online Library
The effective catalytic activity of organoaluminum compounds for the monohydroboration of
carbodiimides has been demonstrated. Two aluminum complexes, 2 and 3, were …

Stabilization of reactive Co4O4 cubane oxygen-evolution catalysts within porous frameworks

AI Nguyen, KM Van Allsburg… - Proceedings of the …, 2019 - National Acad Sciences
A major challenge to the implementation of artificial photosynthesis (AP), in which fuels are
produced from abundant materials (water and carbon dioxide) in an electrochemical cell …

Mechanistic study of nucleation enhancement in atomic layer deposition by pretreatment with small organometallic molecules

C de Paula, NE Richey, L Zeng, SF Bent - Chemistry of Materials, 2019 - ACS Publications
Thermal atomic layer deposition (ALD) of metals on metal oxide surfaces typically suffers
from nucleation delays that result in poor-quality films. The poor nucleation may be caused …