The magnetocaloric effect and its most straightforward application, magnetic refrigeration,
are topics of current interest due to the potential improvement of energy efficiency of cooling …

Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

This first introduction to the rapidly growing field of molecular magnetism is written with
Masters and PhD students in mind, while postdocs and other newcomers will also find it an …

This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Four 52-metal-ion 3d–4f cluster complexes featuring a common core of Ln42M10 (Ln=
Gd3+, Dy3+; M= Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions …

The hydrolysis of Ln (ClO4) 3 in the presence of acetate leads to the assembly of the three
largest known lanthanide-exclusive cluster complexes,[Nd104 (ClO4) 6 (CH3COO) 60 (μ3 …

Recent years have witnessed a terrific increase in the number of molecule-based materials
proposed as magnetic refrigerants for liquid-helium temperatures.[1–15] Refrigeration …

The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …

Two 24-nuclear lanthanide clusters, Gd24 and Dy24 were obtained and structurally
characterized. Magnetic investigations reveal that Gd24 exhibits the largest entropy change …