Molecular spins for quantum computation

A Gaita-Ariño, F Luis, S Hill, E Coronado - Nature chemistry, 2019 - nature.com
Spins in solids or in molecules possess discrete energy levels, and the associated quantum
states can be tuned and coherently manipulated by means of external electromagnetic …

Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

CAP Goodwin, F Ortu, D Reta, NF Chilton, DP Mills - Nature, 2017 - nature.com
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

Spin–phonon coupling and magnetic relaxation in single-molecule magnets

JGC Kragskow, A Mattioni, JK Staab, D Reta… - Chemical Society …, 2023 - pubs.rsc.org
Electron–phonon coupling is important in many physical phenomena, eg photosynthesis,
catalysis and quantum information processing, but its impacts are difficult to grasp on the …

Molecular magnetism

NF Chilton - Annual Review of Materials Research, 2022 - annualreviews.org
Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Ab initio prediction of high-temperature magnetic relaxation rates in single-molecule magnets

D Reta, JGC Kragskow, NF Chilton - Journal of the American …, 2021 - ACS Publications
Organometallic molecules based on [Dy (CpR) 2]+ cations (where CpR is a substituted
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …

Multifunctional Helicene‐Based Ytterbium Coordination Polymer Displaying Circularly Polarized Luminescence, Slow Magnetic Relaxation and Room Temperature …

K Dhbaibi, M Grasser, H Douib, V Dorcet… - Angewandte …, 2023 - Wiley Online Library
The combination of physical properties sensitive to molecular chirality in a single system
allows the observation of fascinating phenomena such as magneto‐chiral dichroism (MChD) …

Spin states, vibrations and spin relaxation in molecular nanomagnets and spin qubits: a critical perspective

L Escalera-Moreno, JJ Baldoví, A Gaita-Arino… - Chemical …, 2018 - pubs.rsc.org
Very recently the closely related fields of molecular spin qubits, single ion magnets and
single atom magnets have been shaken by unexpected results. We have witnessed a jump …

Field-and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet

YS Ding, KX Yu, D Reta, F Ortu, REP Winpenny… - Nature …, 2018 - nature.com
Understanding quantum tunnelling of the magnetisation (QTM) in single-molecule magnets
(SMMs) is crucial for improving performance and achieving molecule-based information …