Bioplastics for a circular economy

JG Rosenboom, R Langer, G Traverso - Nature Reviews Materials, 2022 - nature.com
Bioplastics—typically plastics manufactured from bio-based polymers—stand to contribute to
more sustainable commercial plastic life cycles as part of a circular economy, in which virgin …

Bio-based polymers with performance-advantaged properties

RM Cywar, NA Rorrer, CB Hoyt, GT Beckham… - Nature Reviews …, 2022 - nature.com
Bio-based compounds with unique chemical functionality can be obtained through selective
transformations of plant and other non-fossil, biogenic feedstocks for the development of …

Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers

C Zhang, X Geng, X Zhang, Y Gnanou… - Progress in Polymer …, 2023 - Elsevier
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …

Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Sequence control from mixtures: switchable polymerization catalysis and future materials applications

AC Deacy, GL Gregory, GS Sulley… - Journal of the …, 2021 - ACS Publications
There is an ever-increasing demand for higher-performing polymeric materials
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …

CO 2-fixation into cyclic and polymeric carbonates: principles and applications

AJ Kamphuis, F Picchioni, PP Pescarmona - Green chemistry, 2019 - pubs.rsc.org
The reaction between carbon dioxide and epoxides is an attractive pathway for CO2-
utilisation as it can lead to the formation of two different, yet valuable, products: cyclic and …

Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

V Aomchad, À Cristòfol, F Della Monica, B Limburg… - Green …, 2021 - pubs.rsc.org
Cyclic organic carbonates are among the most widely studied targets in the nonreductive
conversion of carbon dioxide using oxiranes as the common reaction partners. Apart from …

Sustainable polymers from renewable resources

Y Zhu, C Romain, CK Williams - Nature, 2016 - nature.com
Renewable resources are used increasingly in the production of polymers. In particular,
monomers such as carbon dioxide, terpenes, vegetable oils and carbohydrates can be used …

Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

AC Deacy, AFR Kilpatrick, A Regoutz, CK Williams - Nature chemistry, 2020 - nature.com
Carbon dioxide and epoxide copolymerization is an industrially relevant means to valorize
waste and improve sustainability in polymer manufacturing. Given the value of the polymer …