The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …

This review summarizes the recent progress in coordination and organometallic chemistry
involving metal complexes of chelating diarylamido phosphine ligands, including bidentate …

While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …

β-Diketiminates are widely used supporting ligands for building a range of metal complexes
with different oxidation states, structures, and reactivities. This Perspective summarizes the …

A library of low-coordinate titanium and vanadium complexes containing terminal metal−
ligand multiply bonded functionalities such as alkylidenes, alkylidynes, and imides have …

Carbon− carbon bond-forming reductive elimination of biphenyl is observed upon two-
electron oxidation of the [ZrIVPh2 (ap) 2] 2-dianion. Crossover experiments confirm that the …

The novel versatile cobalt (I) tris-carbene complex [(TIMENxyl) Co] Cl (1)(where TIMEN=(tris
[2-(3-arylimidazol-2-ylidene) ethyl] amine) reacts with CO, one-electron oxidizers such as …

In all metallofullerenes known before this work, metal atoms form single highly polar bonds
with non-metal atoms in endohedral cluster. This is rather surprising for titanium taking into …

Structurally authenticated, terminal lanthanide–ligand multiple bonds are rare and expected
to be highly reactive. Even capped with an alkali metal cation, poor orbital energy matching …

A series of cyclometalated iridium complexes with β-ketoiminate and β-diketiminate ligands
are described. Two different cyclometalating (C^ N) ligands 2-phenylpridine (ppy) and 2 …