Conspectus Catalytic reactions that construct carbon–nitrogen bonds are one of central
themes in both synthetic and medicinal chemistry since the obtainable nitrogen-containing …

The development of catalytic enantioselective transformations, enabling the construction of
complex molecular scaffolds from simple precursors, has been a long-standing challenge in …

Direct C–H functionalization has recently emerged as one of the most efficient strategies to
access structurally complex molecules from readily accessible feedstocks in an atom-and …

Ru (II)-catalyzed enantioselective C–H functionalization involving an enantiodetermining C–
H cleavage step remains undeveloped. Here we describe a Ru (II)-catalyzed …

Enantioselective C− H activation has surfaced as a transformative toolbox for the efficient
assembly of chiral molecules. However, despite of major advances in rhodium and …

Among sulfoximine derivatives containing a chiral sulfur center, benzothiadiazine‐1‐oxides
are important for applications in medicinal chemistry. Here, we report that the combination of …

The past decade has witnessed a rapid progress in asymmetric C− H activation. However,
the enantioselective C− H alkoxylation and amination with alcohols and free amines …

Enantioselective C–H functionalization is a powerful tool for synthesizing chiral molecules.
In the past few years, the combination of high-valent group 9 metals with achiral Cpx ligands …

Satoh–Miura reaction is an important method for extending π‐systems by forging multi‐
substituted benzene rings via double aryl C− H activation and annulation with alkynes …

Transition-metal-catalyzed asymmetric C–H activation reactions generally rely on the design
of ligands with sterically bulky groups to create a chiral environment for enantioinduction …