Although chemically binding interatomic interactions are the basis for chemistry as a whole,
the understanding of the nature of the chemical bond is much less advanced than the …

Abstract Free borylenes (R–B:) have only been spectroscopically characterized in the gas
phase or in matrices at very low temperatures. However, in recent years, a few mono‐and …

The results of an energy decomposition analysis of various classes of donor–acceptor
complexes of transition metals and main-group elements are discussed. It is shown that the …

Over the past decade, transition metal complexes of boron have become established as the
fourth class of compounds involving direct metal–boron interactions. In contrast to the other …

Since the publication of the last review in 1998, the transition‐metal chemistry of boron has
continued to raise unceasing interest. Boryl complexes, representing the most extensive …

Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond | Journal of
the American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In …

The results of an energy partitioning analysis of three classes of transition metal complexes
are discussed. They are (i) neutral and charged isoelectronic hexacarbonyls TM (CO) 6q …

The metal-ligand bonds of the title compounds have been investigated with the help of an
energy partitioning analysis at the DFT level. It was found that the attractive orbital …

Reduction of carbene‐borane adduct [(cAAC) BBr2 (CN)](cAAC= 1‐(2, 6‐diisopropylphenyl)‐
3, 3, 5, 5‐tetramethylpyrrolidin‐2‐ylidene) cleanly yielded the tetra (cyanoborylene) species …

The equilibrium geometries and first TM− ER bond dissociation energies of 35 transition
metal complexes with group-13 ligand atoms [(CO) 4Fe− ECp],[(CO) 4Fe− EN (SiH3) …