Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …

Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Herein, we report an end-to-end process including synthesis, work-up, purification, and post-
purification with minimal human intervention using Negishi coupling as a key transformation …

Ynamides are fascinating small molecules with complementary reactivities under radical,
ionic, and metal-catalyzed conditions. We report herein synthetic and DFT investigations of …

Herein we describe the synthesis and reactivity of rhodium catalysts with the very bulky
cyclopentadienyl ligand C8H3tBu4 (designated as tBu4Cp). The reaction of [Rh (cod) Cl] 2 …

Recent advances in the chemistry of bulky bisphosphane ligands related to the dppf motif
are summarized in this review covering the literature from 1981 to 2020 related to over 220 …

Semiconductor quantum dots (QDs) exhibit exciting photophysical properties for a wide
variety of applications in the field of energy conversion, lighting, and more recently quantum …

The development of catalysts for stereospecific polymerization of 1, 3-dienes is an area of
interest due to the robust nature of poly (1, 3-diene) s' physical and mechanical properties …

The ligand, P (o-tolyl) 3, is ubiquitous in applied synthetic chemistry and catalysis,
particularly in Pd-catalyzed processes, which typically include Pd (OAc) 2 (most commonly …