Poly-N-heterocyclic carbene complexes with applications in aqueous media
The discovery and development of N-heterocyclic carbenes is no doubt one of the biggest
success stories in the era of modern chemistry. In the last three decades, poly-N-heterocyclic …
success stories in the era of modern chemistry. In the last three decades, poly-N-heterocyclic …
Transformations of carbon dioxide under homogeneous catalysis conditions (a review)
DN Gorbunov, MV Nenasheva, MV Terenina… - Petroleum …, 2022 - Springer
In view of the growing environmental concerns and the need to involve alternative sources
of raw materials in the chemical industry, intensive research efforts in the last decades have …
of raw materials in the chemical industry, intensive research efforts in the last decades have …
Hydrogenation of CO2 to Formate using a Simple, Recyclable, and Efficient Heterogeneous Catalyst
GH Gunasekar, KD Jung, S Yoon - Inorganic Chemistry, 2019 - ACS Publications
Today, one of the most imperative targets to realize the conversions of CO2 in industry is the
development of practically viable catalytic systems that demonstrate excellent activity …
development of practically viable catalytic systems that demonstrate excellent activity …
Mechanistic insight into the electron-donation effect of modified ZIF-8 on Ru for CO2 hydrogenation to formic acid
X Hu, M Luo, M ur Rehman, J Sun, HASM Yaseen… - Journal of CO2 …, 2022 - Elsevier
The electron-donating effect of supports on active metals has been reported to be beneficial
to improve catalytic activity of heterogenized molecule catalysts for CO 2 hydrogenation to …
to improve catalytic activity of heterogenized molecule catalysts for CO 2 hydrogenation to …
Metal–Ligand Cooperation in Cp*Ir-Pyridylpyrrole Complexes: Rational Design and Catalytic Activity in Formic Acid Dehydrogenation and CO2 Hydrogenation under …
XF Mo, C Liu, ZW Chen, F Ma, P He, XY Yi - Inorganic Chemistry, 2021 - ACS Publications
Interconversion between CO2+ H2 and FA/formate is the most promising strategy for the
fixation of carbon dioxide and reversible hydrogen storage; however, FA dehydrogenation …
fixation of carbon dioxide and reversible hydrogen storage; however, FA dehydrogenation …
Carboxylate-Assisted β-(Z) Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed by a Zwitterionic Bis-NHC Rhodium(III) Complex
The zwitterionic compound [Cp* RhCl {(MeIm) 2CHCOO}] is an efficient catalyst for the
hydrosilylation of terminal alkynes with excellent regio-and stereoselectivity toward the less …
hydrosilylation of terminal alkynes with excellent regio-and stereoselectivity toward the less …
Hydrogenation of CO2 by a Bifunctional PC(sp3)P Iridium(III) Pincer Complex Equipped with Tertiary Amine as a Functional Group
S Gelman‐Tropp, E Kirillov… - … A European Journal, 2023 - Wiley Online Library
Reversible hydrogen storage in the form of stable and mostly harmless chemical substances
such as formic acid (FA) is a cornerstone of a fossil fuels‐free economy. In the past, we have …
such as formic acid (FA) is a cornerstone of a fossil fuels‐free economy. In the past, we have …
Catalytic applications of zwitterionic transition metal compounds
R Puerta-Oteo, AI Ojeda-Amador, MV Jiménez… - Dalton …, 2022 - pubs.rsc.org
This frontiers article highlights recent developments on the application of transition metal-
based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic …
based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic …
Mechanistic Insights on the Functionalization of CO2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate‐Functionalized Bis‐NHC Catalyst
AI Ojeda‐Amador, J Munarriz… - …, 2019 - Wiley Online Library
Abstract The zwitterionic complex [Cp* IrCl {(MeIm) 2CHCOO}](1) efficiently catalyzes the
selective hydrosilylation of CO2 to afford the corresponding silylformate. The best reaction …
selective hydrosilylation of CO2 to afford the corresponding silylformate. The best reaction …
Molecular water oxidation catalysis by zwitterionic carboxylate bridge-functionalized bis-NHC iridium complexes
R Puerta-Oteo, MV Jiménez… - Catalysis Science & …, 2019 - pubs.rsc.org
Zwitterionic water-soluble [Cp* IrIIICl {(MeIm) 2CHCOO}] and [IrI (cod){(MeIm) 2CHCOO}]
complexes featuring a carboxylate bridge-functionalized bis-N-heterocyclic carbene ligand …
complexes featuring a carboxylate bridge-functionalized bis-N-heterocyclic carbene ligand …