Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …

Sequential reactions of heptadentate phosphinoamine LH3 with rare-earth metal tris-alkyl
precursor (Me3SiCH2) 3Ln (THF) 2 (Ln= Sc, Lu, Yb, Y, Gd) and a low-valent cobalt complex …

The Co (− I) dihydrogen complexes,[(η2-H2) CoML]−, where ML is the group 13
metalloligand, N (o-(NCH2PiPr2) C6H4) 3M, and M is Al, Ga, or In, were previously reported …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

We present three heterobimetallic complexes containing an isostructural nickel center and a
lutetium ion in varying coordination environments. The bidentate iPr2PCH2NHPh and …

Iron tetraphenylporphyrin complex modified with four trimethylammonium groups (Fe-p-
TMA) is found to be capable of catalyzing the eight-electron eight-proton reduction of CO2 to …